34434-27-0Relevant articles and documents
Di-t-BUTYL NITROXYL-RADICAL INDUCED HOMOLYSIS OF POLYFLUORODIACYL PEROXIDES
Zhao, Cheng-Xue,Chen, Guo-Fei,Wang, Xian-Shan,Jiang, Xi-kui
, p. 417 - 424 (1986)
In the presence of di-t-butyl nitroxide (DTBNO) polyfluoro-diacylperoxides undergo rapid decomposition in n-pentane or CClF2-CCl2F at -50 to +20 degC.The reactions are first order in peroxide and DTBNO.On the basis of ESR observation of t-butyl polyfluoroalkyl nitroxides as well as product analysis, it appears that the decomposition processes involve DTBNO induced homolysis of the peroxy bonds followed by product formation steps.