3454-66-8Relevant articles and documents
Dithiophosphate radical terminated mercaptosilane coupling agent as well as synthesis method and application thereof
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Paragraph 0027-0028; 0030; 0031-0032; 0034, (2020/12/30)
The invention belongs to a silane coupling agent, and particularly relates to a dithiophosphate radical terminated mercaptosilane coupling agent as well as a synthesis method and an application thereof. The dithiophosphate radical terminated mercaptosilane coupling agent has a structure as shown in a formula (I) which is described in the specification. According to the dithiophosphate radical terminated mercaptosilane coupling agent shown in the formula (I), the interaction between a polymer and filler can be enhanced, the hysteresis loss of a rubber material is remarkably reduced, the Payne effect of a rubber material is reduced, and the dispersity of white carbon black is improved, so that the oil consumption and the emission of carbon dioxide in the tire driving process are reduced, andthe wear resistance of the tire is enhanced; meanwhile, the dithiophosphate radical terminated mercaptosilane coupling agent provided by the invention has the effect of promoting vulcanization, and can reduce the energy loss in the vulcanization process.
Synthesis, characterization, and oxygen atom transfer reactions of {HB(Me2C3N2H)3}MoO{S 2P(OR)2} and {HB(Me2C3N2H)3}MoO 2{η1-S2P(OEt)2}
Roberts, Sue A.,Young, Charles G.,Cleland Jr.,Ortega, Richard B.,Enemark, John H.
, p. 3044 - 3051 (2008/10/08)
The compounds {HB(Me2pz)3}MoO{S2P(OEt)2} (1a) and {HB(Me2pz)3}MoO2{S2P(OEt) 2} (2) containing bidentate and monodentate S2P(OEt)2- ligands, respectively, have been prepared by the reaction of Mo2O3{S2P(OEt)2}4 with K{HB(Me2pz)3} {HB(Me2pz)3}MoO{S2P(OEt)2} and its analogue {HB(Me2pz)3}MoO{S2P(OMe)2} have also been prepared in higher yield by the reaction of Mo2O3{S2P(OEt)2}4 with Ph3P followed by reaction with K{HB(Me2pz)3}. Both 1a and 2 have been structurally characterized by X-ray crystallography. The blue Mo(IV) compound 1a crystallizes in the monoclinic space group P21/c with a = 17.987 (3) ?, b = 8.219 (3) ?, c = 18.681 (7) ?, β = 104.88 (2)°, and Z = 4. The molybdenum atom is six-coordinate and facially coordinated by the tridentate HB(Me2pz)3- ligand, by one terminal oxo ligand (Mo=O = 1.644 (6) ?) and by the bidentate S2P(OEt)2- ligand. The gold-colored Mo(VI) complex 2 crystallizes as the toluene hemisolvate in the triclinic space group P1 with a = 8.421 (1) ?, b = 12.654 (6) ?, c = 15.240 (5) ?, α = 87.77 (3)°, β = 81.36 (2)°, γ = 74.37 (3)°, and Z = 2. The molybdenum atom is six-coordinate with a tridentate HB(Me2Pz)3- ligand, two terminal oxo ligands (Mo=O = 1.690 (2) and 1.697 (2) ?), and a monodentate S2P(OEt)2- ligand. The S2P(OEt)2- ligand adopts an extended geometry, and the uncoordinated sulfur atom is 5.42 ? from the molybdenum atom. Compound 1a reduces Me2SO to Me2S. The kinetic data can be fit to a second-order rate law with k = 5.46 (6) × 10-5 (M s)-1 in toluene at 40°C. Activation parameters determined from plots of ln (k/T) vs 1/T are ΔH? = 15.3 (2) kcal mol-1 and ΔS? = -29 (2) cal (mol K)-1. The large negative entropy of activation indicates that an associative mechanism is operative. Compound 2 oxidizes Ph3P to Ph3PO. Again, a second-order rate law is followed: k = 3.4 (1) × 10-3 (M s)-1 in toluene at 25°C. Both complexes catalyze the oxidation of Ph3P by Me2SO.
Mono- and di-thiophosphate esters containing an isoxazolinone ring and compositions and methods containing the same
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, (2008/06/13)
Mono- and di-thiophosphate esters having an isoxazolinone system attached at its 2-position through an optionally alkyl- or phenyl-substituted methylene or ethylene group to the sulphur or to one of the sulphur atoms are useful as insecticides and/or acar