345949-81-7

Basic information

• Product Name: cis-(2R,3R)-t-butyl 3-phenyltetrahydrofuran-2-carboxylate
• Synonyms: cis-(2R,3R)-t-butyl 3-phenyltetrahydrofuran-2-carboxylate
• CAS NO: 345949-81-7
• Molecular Weight: 248.322
• Mol File: 345949-81-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: cis-(2R,3R)-t-butyl 3-phenyltetrahydrofuran-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: cis-(2R,3R)-t-butyl 3-phenyltetrahydrofuran-2-carboxylate(345949-81-7)
• EPA Substance Registry System: cis-(2R,3R)-t-butyl 3-phenyltetrahydrofuran-2-carboxylate(345949-81-7)

Safety Data

• Hazardous Substances Data: 345949-81-7(Hazardous Substances Data)

Upstream product

• 4436-23-1 2-phenyloxetane 
• 35059-50-8 t-butyl diazoacetate 
• 106760-61-6 (R)-(+)-2-Phenyloxetane 
• 100306-33-0 (1R)-3-chloro-1-phenylpropanol 

Relevant articles and documents

Applications of planar-chiral heterocycles in enantioselective catalysis: Cu(I)/bisazaferrocene-catalyzed asymmetric ring expansion of oxetanes to tetrahydrofurans

A planar-chiral, C2-symmetric bisazaferrocene ligand is shown to control the stereochemistry of Cu(I)-catalyzed ring expansions of oxetanes to tetrahydrofurans.

Asymmetric Carbene C-O Insertion Using Optically Active Bipyridine-Copper Complex as a Catalyst. Ring Expansion of Oxetanes to Tetrahydrofurans

Copper complex of (7R,7R')-di(1-t-butyldimethylsiloxy-1-methylethyl)-6,6',7,7'-tetrahydro-5H,5'H-2,2'-bi-1,1'-pyridine (3) was found to be an effective catalyst for asymmetric carbene insertion reaction into the C-O bond of oxetanes.For example, the react