3462-52-0Relevant articles and documents
FLUORIDE ION INDUCED REACTIONS OF ORGANOSILANES: THE PREPARATION OF MONO AND DICARBONYL COMPOUNDS FROM β-KETOSILANES.
Fiorenza, Mariella,Mordini, Alessandro,Papaleo, Sandro,Pastorelli, Stefania,Ricci, Alfredo
, p. 787 - 788 (1985)
β-ketosilanes react with a variety of carbon electrophiles in the presence of CsF to give mono- and dicarbonyl derivatives in reasonably good yields.
In tandem or alone: A remarkably selective transfer hydrogenation of alkenes catalyzed by ruthenium olefin metathesis catalysts
Zieliski, Grzegorz Krzysztof,Samojlowicz, Cezary,Wdowik, Tomasz,Grela, Karol
supporting information, p. 2684 - 2688 (2015/04/14)
A system for transfer hydrogenation of alkenes, composed of a ruthenium metathesis catalyst and HCOOH, is presented. This operationally simple system can be formed directly after a metathesis reaction to effect hydrogenation of the metathesis product in a single-pot. These hydrogenation conditions are applicable to a wide range of alkenes and offer remarkable selectivity. This journal is
Reaction of tetracarbonyl(π-allyl)manganese with carbon nucleophiles
Vaughan, William S.,Gu, Henry H.,McDaniel, Keith F.
, p. 1885 - 1888 (2007/10/03)
Nucleophilic attack on tetracarbony (π-allyl)manganese takes place at the terminus of the π-system, generating allylated products in 44-95% yield after oxidation. Stabilized nucleophiles (pK(a) 12-20) give mainly bis allylation whereas nonstabilized nucleophiles (pKa 25-35) give mono allylation.