34622-58-7 Usage
Description
ORBENCARB is a monothiocarbamic ester that features carbamothioic S-acid substituted by two ethyl groups at the nitrogen atom and a 2-chlorobenzyl group at the sulfur atom. It is a chemical compound with potential applications in various industries due to its unique properties.
Uses
1. Used in Pharmaceutical Industry:
ORBENCARB is used as a pharmaceutical compound for its potential therapeutic applications. Its unique structure allows it to interact with specific biological targets, making it a candidate for the development of new drugs.
2. Used in Chemical Research:
ORBENCARB serves as a valuable compound in chemical research, particularly in the study of monothiocarbamic esters and their reactions. It can be used to explore new synthetic pathways and understand the reactivity of similar compounds.
3. Used in Agrochemical Industry:
ORBENCARB may have potential applications in the agrochemical industry as a component in the development of new pesticides or herbicides. Its specific properties could be harnessed to target and control pests or weeds effectively.
4. Used in Material Science:
In the field of material science, ORBENCARB could be utilized in the development of new materials with unique properties, such as improved stability or reactivity. Its chemical structure may contribute to the creation of advanced materials for various applications.
5. Used in Environmental Applications:
ORBENCARB may also find use in environmental applications, such as in the remediation of contaminated sites or the development of new methods for waste treatment. Its chemical properties could be employed to target and neutralize harmful substances in the environment.
Metabolic pathway
When 14C-orbencarb is applied to the soil surface,
plants absorb the radioactivity and orbencarb is rapidly
transformed to water-soluble metabolites in the plants.
The major metabolites identified are 2-chlorobenzyl
alcohol and 2-chlorobenzoic acid both in free and
conjugated forms, 2-chlorobenzyl sulfonic acid and
methyl 2-chlorobenzylsulfone. Hydroxylated
metabolites at the phenyl ring and N-vinyl metabolite
are found in soybean plants. Orbencarb degrades
more rapidly in soils under upland conditions than in
soils under flooded conditions. The major degradation
products in the soils are orbencarb sulfoxide,
monodesmethylorbencarb, methyl-2-
chlorobenzylsulfoxide, methyl-2-chlorobenzylsulfone,
and 2-chlorobenzylsulfonic acid.
Check Digit Verification of cas no
The CAS Registry Mumber 34622-58-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,4,6,2 and 2 respectively; the second part has 2 digits, 5 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 34622-58:
(7*3)+(6*4)+(5*6)+(4*2)+(3*2)+(2*5)+(1*8)=107
107 % 10 = 7
So 34622-58-7 is a valid CAS Registry Number.
InChI:InChI=1/C12H16ClNOS/c1-3-14(4-2)12(15)16-9-10-7-5-6-8-11(10)13/h5-8H,3-4,9H2,1-2H3
34622-58-7Relevant articles and documents
Solvent-assisted thiocarboxylation of amines and alcohols with carbon monoxide and sulfur under mild conditions
Mizuno, Takumi,Iwai, Toshiyuki,Ishino, Yoshio
, p. 9157 - 9163 (2007/10/03)
DMSO or DMF as a solvent strongly accelerated the thiocarboxylation of amines and alcohols with carbon monoxide and sulfur. Under mild conditions (1 atm, 20°C), this thiocarboxylation of amines assisted by DMSO with carbon monoxide and sulfur has been developed into a practical and convenient synthetic method for S-alkyl thiocarbamates in good to excellent yields, including EPTC, thiobencarb, orbencarb, and molinate (herbicides). DMF also showed the similar solvent effect. NMP slightly decreased the effect for the thiocarboxylation of amines, and the yield of S-alkyl thiocarbamate was lowered in DMAc. Surprisingly, no formation of S-alkyl thiocarbamate was observed at the use of the other solvents, such as THF, hexane, toluene, AcOEt, MeCN, MeOH, and H 2O. The present solvent-assisted thiocarboxylation with carbon monoxide and sulfur could be also applied to a new synthesis of S-alkyl O-alkyl carbonothioates from alcohols under mild conditions (1 atm, 20°C) in DMF using DBU (1,8-diazabicyclo[5.4.0]undec-7-ene).
Facile S-alkyl thiocarbamate synthesis by a novel DBU-assisted carbonylation of amines with carbon monoxide and sulfur
Mizuno, Takumi,Takahashi, Junko,Ogawa, Akiya
, p. 1327 - 1331 (2007/10/03)
A novel DBU-assisted carbonylation of amines with carbon monoxide and sulfur has been developed for the synthesis of S-alkyl thiocarbamates. In the presence of DBU (1,8-diazabicyclo[5.4.0]undec-7-ene), S-alkyl thiocarbamates are synthesized in excellent yields from amines, carbon monoxide, sulfur, and alkyl halides under mild conditions (1 atm, 20°C). In the absence of DBU, however, no formation of S-alkyl thiocarbamate is observed. The present DBU-assisted carbonylation can also be applied to new synthetic methods for benthiocarb and orthobencarb (herbicides) and carbamoyl chlorides.
Facile synthesis of S-alkyl thiocarbamates through reaction of carbamoyl lithium with elemental sulfur
Mizuno, Takumi,Nishiguchi, Ikuzo,Okushi, Tsuneo,Hirashima, Tsuneaki
, p. 6867 - 6868 (2007/10/02)
Efficient synthesis of S-alkyl thiocarbamates was developed. The key step of this synthetic method is a conversion of carbamoyl lithium, generated from lithium dialkylamide and carbon monoxide, to lithium thiocarbamate by addition of elemental sulfur.
