346735-31-7

Basic information

• Product Name: Rh(CO)(P(C₆H₅)3)2C₆H₄C(CH₃)(C₆H₅)CHCH₂
• CAS NO: 346735-31-7
• Molecular Weight: 862.793
• Mol File: 346735-31-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Rh(CO)(P(C₆H₅)3)2C₆H₄C(CH₃)(C₆H₅)CHCH₂(CAS DataBase Reference)
• NIST Chemistry Reference: Rh(CO)(P(C₆H₅)3)2C₆H₄C(CH₃)(C₆H₅)CHCH₂(346735-31-7)
• EPA Substance Registry System: Rh(CO)(P(C₆H₅)3)2C₆H₄C(CH₃)(C₆H₅)CHCH₂(346735-31-7)

Safety Data

• Hazardous Substances Data: 346735-31-7(Hazardous Substances Data)

Upstream product

• 17185-29-4 carbonylhydridetris(triphenylphosphine)rhodium(I) 
• 25152-47-0 2,2-diphenyl-1-methylenecyclopropane 

Relevant articles and documents

Hydrido-Rhodium(I) and -Iridium(I) complex promoted ring-opening isomerization of unsymmetrically substituted methylenecyclopropanes into 1,3-dienes. Structures of intermediates and reaction pathways

2-Phenyl-1-methylenecyclopropane and 2,2-diphenyl-1-methylenecyclopropane react with MH(CO)(PPh3)3 (M = Rh, Ir) to produce 1,3-dienes or the intermediate Rh and Ir complexes having a 3-butenyl ligand, depending on the conditions. The structures and chemical properties of the obtained complexes suggest plausible pathways for the ring-opening isomerization of the methylenecyclopropanes to the corresponding dienes.