34788-82-4

Basic information

• Product Name: EUROPIUM TRIS[3-(HEPTAFLUOROPROPYLHYDROXYMETHYLENE)-(+)-CAMPHORATE]
• Synonyms: TRIS[3-(HEPTAFLUOROPROPYLHYDROXYMETHYLENE)-D-CAMPHORATO] EUROPIUM(III) DERIVATIVE 98%;Tris-[3-(2,2,3,3,4,4,4-heptafluoro-1-oxobutyl)-1,7;Tris-[3-(2,2,3,3,4,4,4-heptafluoro-1-oxobutyl)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-onato-O,O']europium;(fluoropropylhydroxymethylene)-(+)-camphorato europium;Eu(hfc)3, Tris[3-(heptafluoropropylhydroxymethylene)-d-camphorato]europium(III);Eu(hfc)3, Europium(III) tris[3-(heptafluoropropylhydroxymethylene)-d-camphorate], Tris[3-(heptafluoropropylhydroxymethylene)-d-camphorato]europium(III);Tris[3-(heptafluoropropylhydroxymethylene)-d-camphorato], europium(III) derivative,98%;Tris[3-(heptafluoropropylhydroxymethylene)-d-camphorato], europium(III) derivative, 98%
• CAS NO: 34788-82-4
• Molecular Formula: C42H42EuF21O6
• Molecular Weight: 1193.71
• EINECS: 252-214-0
• Mol File: 34788-82-4.mol
• Article Data: 0

Chemical Properties

• Melting Point: 156-158 °C(lit.)
• Boiling Point: 285.6°Cat760mmHg
• Flash Point: 126.6°C
• Appearance: /
• Density: g/cm³
• Storage Temp.: 2-8°C
• CAS DataBase Reference: EUROPIUM TRIS[3-(HEPTAFLUOROPROPYLHYDROXYMETHYLENE)-(+)-CAMPHORATE](CAS DataBase Reference)
• NIST Chemistry Reference: EUROPIUM TRIS[3-(HEPTAFLUOROPROPYLHYDROXYMETHYLENE)-(+)-CAMPHORATE](34788-82-4)
• EPA Substance Registry System: EUROPIUM TRIS[3-(HEPTAFLUOROPROPYLHYDROXYMETHYLENE)-(+)-CAMPHORATE](34788-82-4)

Safety Data

• Safety Statements: S22:Do not inhale dust.; S24/25:Avoid contact with skin and eyes.
• WGK Germany: 3
• F: 3-10
• Hazardous Substances Data: 34788-82-4(Hazardous Substances Data)

Usage

Description

EUROPIUM TRIS[3-(HEPTAFLUOROPROPYLHYDROXYMETHYLENE)-(+)-CAMPHORATE], also known as Eu(hfc)3, is a complex compound that serves as an optically active NMR shift reagent. It is characterized by its unique structure, which includes europium as the central metal ion and three (+)-camphorate ligands, each modified with a heptafluoropropylhydroxymethylene group. EUROPIUM TRIS[3-(HEPTAFLUOROPROPYLHYDROXYMETHYLENE)-(+)-CAMPHORATE] plays a crucial role in the analysis of chiral molecules, providing valuable information on their stereochemistry.

Uses

Used in Chiral Analysis:
EUROPIUM TRIS[3-(HEPTAFLUOROPROPYLHYDROXYMETHYLENE)-(+)-CAMPHORATE] is used as an optically active NMR shift reagent for the 1H NMR analysis to determine the enantiomeric purities of various chiral compounds. Its application is particularly relevant for the precursors of trisporic acids A and B, as well as related products. EUROPIUM TRIS[3-(HEPTAFLUOROPROPYLHYDROXYMETHYLENE)-(+)-CAMPHORATE]'s ability to differentiate between enantiomers allows for accurate determination of their purity, which is essential in the synthesis and development of enantiomerically pure compounds.
Used in Determining Optical Purity:
In the field of organic chemistry, the optical purity of a compound is a critical parameter that influences its biological activity and potential applications. EUROPIUM TRIS[3-(HEPTAFLUOROPROPYLHYDROXYMETHYLENE)-(+)-CAMPHORATE] is used as an optically active NMR shift reagent to determine the optical purity of racemic 6,7-dichloro-5-methoxy-2-methyl-2-phenyl-1 indanone. This information is vital for assessing the compound's suitability for further chemical reactions or pharmaceutical applications.
Used in Assessing Epimeric Purity:
Epimeric purity is another important aspect of stereochemistry, particularly in the context of carbohydrate chemistry. EUROPIUM TRIS[3-(HEPTAFLUOROPROPYLHYDROXYMETHYLENE)-(+)-CAMPHORATE] is used as an optically active NMR shift reagent to determine the epimeric purity of 4-methylsulfinylbutylglucosinolate. This analysis is crucial for understanding the compound's stereochemistry and its potential applications in various industries, such as pharmaceuticals, agrochemicals, and materials science.

InChI:InChI=1/3C14H15F7O2.Eu/c3*1-10(2)6-4-5-11(10,3)8(22)7(6)9(23)12(15,16)13(17,18)14(19,20)21;/h3*6,23H,4-5H2,1-3H3;/q;;;+3/p-3/b2*9-7+;9-7-;/t3*6?,11-;/m000./s1