34793-63-0Relevant articles and documents
Tandem Michael-anti-Michael Addition-Mediated Orthogonal Strapping of Diynones: Regioselective Spirocyclopentannulation of Oxindoles and Pyrazolones and DFT Validation
Sarma, Manas Jyoti,Jindani, Sana,Ganguly, Bishwajit,Pabbaraja, Srihari,Mehta, Goverdhan
, p. 884 - 891 (2022/01/11)
An efficient protocol involving the transformation of sequentially generated recursive anions from heterocyclic precursors to orthogonally strap diynones through one pot transition-metal-free spirocyclopentannulation has been devised, employing oxindoles
Ethyl lactate as a renewable carbonyl source for the synthesis of diynones
Solas, Marta,Suárez-Pantiga, Samuel,Sanz, Roberto
supporting information, p. 213 - 218 (2019/01/28)
Ethyl lactate, a sustainable feedstock, serves as a highly attractive building block for the synthesis of value-added chemicals such as skipped diynones and, after gold-catalyzed transposition, conjugated diynones. Green solvents are involved in all steps
Bronsted acid catalyzed and NIS-promoted cyclization of diynones: Selective synthesis of 4-pyrone, 4-pyridone, and 3-pyrrolone derivatives
Qiu, Yi-Feng,Yang, Fang,Qiu, Zi-Hang,Zhong, Mei-Jin,Wang, Li-Jing,Ye, Yu-Ying,Song, Bo,Liang, Yong-Min
, p. 12018 - 12028 (2014/01/06)
Bronsted acid catalyzed tandem cyclization was found to be highly effective for the preparation of a series of polysubstituted 4-pyrones from diynones (yield up to 99%). 4-Pyridone and 3-pyrrolone derivatives were also selectively synthesized by employing NIS and/or Bronsted acid. NIS as an electrophilic reagent could promote these reactions efficiently and rapidly under very mild reaction conditions.