3480-93-1Relevant articles and documents
Synthesis of a sensitive and selective potassium-sensing fluoroionophore
Carpenter, Richard D.,Verkman
supporting information; experimental part, p. 1160 - 1163 (2010/05/18)
"Chemical Equation Presented" An efficient synthesis is reported that delivers in 5 steps and 52% overall yield a new structurally simplified fluorescent K+ sensor with improved K+ sensitivity and selectivity over existing K+ sensors. The synthesis procedure utilizes a new template-directed oxidative C-N bond-forming macrocyclization reaction and reports new approaches to Pd(O), Sandmeyer-like and metal-free aminoarylations, as well as organotitanium additions to vinylogous sulfonates.
Phospha-adamantanes as ligands for organopalladium chemistry: Aminations of aryl halides
Gerristma, David,Brenstrum, Timothy,McNulty, James,Capretta, Alfredo
, p. 8319 - 8321 (2007/10/03)
The use of Pd2dba3·CHCl3 and 1,3,5,7-tetramethyl-2,4,8-trioxa-6-phenyl-6-phospha-adamantane has been shown to facilitate the effective amination of aryl halides with aromatic or aliphatic amines in high yields.
