34807-89-1

Basic information

• Product Name: eta5-Pentamethylcyclopentadienyl manganese tricarbonyl
• CAS NO: 34807-89-1
• Molecular Weight: 274.198
• Mol File: 34807-89-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: eta5-Pentamethylcyclopentadienyl manganese tricarbonyl(CAS DataBase Reference)
• NIST Chemistry Reference: eta5-Pentamethylcyclopentadienyl manganese tricarbonyl(34807-89-1)
• EPA Substance Registry System: eta5-Pentamethylcyclopentadienyl manganese tricarbonyl(34807-89-1)

Safety Data

• Hazardous Substances Data: 34807-89-1(Hazardous Substances Data)

Upstream product

• 86277-32-9 tri-μ-carbonyl-bis(η5-pentamethylcyclopentadienyl)manganese 
• 15321-51-4 diiron nonacarbonyl 
• 118018-15-8 (μ-tin)bis{dicarbonyl(η5-pentamethylcyclopentadienyl)manganese}(Mn-Mn) 

Downstream Products

• 1043044-87-6 (C₅(CH₃)5)Mn(CO)3⁽¹⁺⁾*B(C₆F₅)4^(1-)=(C₅(CH₃)5)Mn(CO)3B(C₆F₅)4 
• 34808-37-2 [Mn(η-C5Me5)(CO)2(PPh3)] 
• 287118-81-4 (η5-C5Me5)Mn(CO)2[Fe(η5-C5H4)2PPh] 
• 114581-56-5 dicarbonyl(pentafluorophenylisocyanide)(η5-pentamethylcyclopentadienyl)manganese 
• 2548-47-2 2,3-diphenyl-1,3-butadiene 

Relevant articles and documents

Multiple Bonds Between Main-Group Elements and Transition Metals, LIX. - Bridging Tin Atoms in Organomanganese Complexes. Formation, Structures, and Reactivity of Manganese-Tin Multiple Bonds

Organomanganese complexes with tin atoms in linear and trigonal-planar coordination environments are accessible by means of two different synthetic methods.Sequential treatment of the complex (η5-C5H4CH3)Mn(CO)2(THF (1a) with tin(II) chloride and zinc dust yields (μ3-Sn)5-C5H4CH3)Mn(CO)2>3 (2a); 2a is also formed from 1a and monostannane, SnH4.The pentamethylcyclopentadienyl derivative 1b yields analogously the two compounds (μ3-Sn)5-C5Me5)Mn(CO)2>3 (2b) and (μ-Sn)5-C5Me5)Mn(CO)2>2 (3b). 2a formally contains two Mn-Sn single bonds and a Mn-Sn double bond (X-ray diffraction study). - Keywords: Bridging tin atoms/ Organomanganese complexes