34825-70-2

Basic information

• Product Name: 1-AMINO-5-HEXENE
• Synonyms: RARECHEM AN KA 1437;1-AMINO-5-HEXENE;Hex-5-en-1-amine
• CAS NO: 34825-70-2
• Molecular Formula: C₆H₁₃N
• Molecular Weight: 99.17
• Mol File: 34825-70-2.mol
• Article Data: 25

Chemical Properties

• Boiling Point: 139.6 °C at 760 mmHg
• Flash Point: 36.8 °C
• Appearance: /
• Density: 0.784 g/cm³
• PKA: 10.60±0.10(Predicted)
• CAS DataBase Reference: 1-AMINO-5-HEXENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-AMINO-5-HEXENE(34825-70-2)
• EPA Substance Registry System: 1-AMINO-5-HEXENE(34825-70-2)

Safety Data

• Hazardous Substances Data: 34825-70-2(Hazardous Substances Data)

Usage

General Description

1-AMINO-5-HEXENE, also known as 1-pentylamine, is a chemical compound that belongs to the group of amines. It is an organic compound with the molecular formula C6H13N and is commonly used as a building block in the synthesis of various pharmaceuticals and other organic compounds. 1-AMINO-5-HEXENE is a clear, colorless liquid with a strong ammonia-like odor and is highly flammable. It is primarily used as a chemical intermediate in the production of pesticides, rubber accelerators, and pharmaceuticals. Additionally, it is used as a corrosion inhibitor in fuel systems, as a lubricant additive, and in the manufacture of fragrances and flavors. Due to its reactivity and potential health hazards, 1-AMINO-5-HEXENE should be handled with care and in accordance with proper safety protocols.

Upstream product

• 821-41-0 5-Hexen-1-ol 
• 4048-33-3 6-amino-1-hexanol 
• 102108-47-4 C₁₃H₁₇N 
• 821-77-2 5-hexenylazide 
• 28487-09-4 hex-5-enamide 
• 1577-22-6 5-hexenoic acid 
• 786-32-3 pent-4-enyl p-nitrobenzenosulfonate 
• 2695-47-8 6-Bromo-1-hexene 
• 64818-36-6 5-hexenyl methanesulfonate 
• 52898-33-6 N-(5-hexenyl)phthalimide 
• 5048-19-1 hex-5-enenitrile 

Downstream Products

• 157099-64-4 N-(hex-5-enyl)hex-5-enamide 
• 1192-29-6 2-ethyl-1-pyrroline 
• 1462-92-6 6-methyl-2,3,4,5-tetrahydro-pyridine 
• 55108-01-5 1-aminohex-trans-4-ene 
• 87156-74-9 1-aminohex-cis-3-ene 
• 109-05-7 2-Methylpiperidin 
• 176171-61-2 Benzyl-hex-5-en-(E)-ylidene-amine 
• 102108-47-4 Hex-5-enyl-[1-phenyl-meth-(E)-ylidene]-amine 
• 81097-32-7 N-hex-5-enyl(4-methylphenyl)sulfonamide 
• 849214-70-6 N^α-Fmoc-N^ε-Boc-lysyl (5-hexenyl)amide 
• 884864-65-7 allyl-[2-(5-benzyloxy-2-hex-5-enylcarbamoyl-3-hydroxy-phenyl)-furan-3-ylmethyl]-carbamic acid tert-butyl ester 
• 202926-14-5 tert-butyl hex-5-en-1-ylcarbamate 
• 145126-90-5 N-benzyl-N-hex-5-enylamine 
• 1190426-46-0 tert-butyl ((2S,3R)-4-(hex-5-en-1-ylamino)-3-hydroxy-1-phenylbutan-2-yl)carbamate 

Relevant articles and documents

Immobilization of a non-heme diiron complex encapsulated in an ammonium-type ionic liquid layer modified on an Au electrode: Reactivity of the electrode for O2 reduction

An unstable diiron(ii,ii) complex possessing O2 binding ability at low temperature was encapsulated and stabilized in an ammonium-type ionic liquid layer polymerized on an electrode. The encapsulated complex revealed catalytic reactivity for four-electron reduction of O2 at an ambient temperature in aqueous solution.

Dual Role of Vinyl Sulfonamides as N-Nucleophiles and Michael Acceptors in the Enantioselective Synthesis of Bicyclic δ-Sultams

A new methodology for the synthesis of enantiomerically enriched bicyclic δ-sultams is described, involving an initial organocatalytic intramolecular aza-Michael reaction of vinyl sulfonamides bearing a conjugated ketone at a remote position. The resulting Michael adducts were then subjected to an intramolecular conjugate addition over the vinyl sulfone moiety, thus rendering the final bicyclic sultams containing two stereocenters. The key point of this strategy relies on the use of vinyl sulfonamides as both, nitrogen nucleophiles and Michael acceptors. The use of phosphazene-derived bases avoided the racemization of the intermediate derivatives, rendering 6-membered ring bicyclic δ-sultams in enantiomerically enriched manner with a small erosion of enantiopurity. Anyway, after recrystallization, final sultams were obtained in almost enantiomerically pure form. Nevertheless, the enantioselective synthesis of either 5-membered ring products or benzofused derivatives was found to be out of the scope of our strategy. (Figure presented.).

Palladium-Catalyzed Aerobic Oxidative Cyclization of Aliphatic Alkenyl Amides for the Construction of Pyrrolizidine and Indolizidine Derivatives

An efficient palladium-catalyzed aerobic oxidative cyclization has been developed to synthesize a variety of pyrrolizidine and indolizidine derivatives from simple aliphatic alkenyl amides in moderate to good yields. The reaction features the capability of accessing various N-heterocycles and the use of molecular oxygen (1 atm) as the green oxidant.