3484-43-3

Basic information

• Product Name: (+/-)-atractylon
• CAS NO: 3484-43-3
• Molecular Weight: 216.323
• Mol File: 3484-43-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (+/-)-atractylon(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-atractylon(3484-43-3)
• EPA Substance Registry System: (+/-)-atractylon(3484-43-3)

Safety Data

• Hazardous Substances Data: 3484-43-3(Hazardous Substances Data)

Upstream product

• 65128-92-9 methyl (1α,4aβ)-6-methoxy-4a-methyl-4-oxo-1,2,3,4,4a,7-hexahydro-1-naphthoate 
• 98466-48-9 (1S,4S,4aS,8aR)-4-Hydroxy-4a-methyl-6-oxo-decahydro-naphthalene-1-carboxylic acid methyl ester 
• 105631-40-1 (4'aR,5'S,8'S,8'aS)-8'a-Methyl-8'-methylsulfanylthiocarboxyoxy-octahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]-5'-carboxylic acid methyl ester 
• 105631-39-8 (4'aS,5'R,8'R,8'aR)-8'-Hydroxy-8'a-methyl-octahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]-5'-carboxylic acid methyl ester 
• 98466-47-8 (1S,4S,4aS)-4-Hydroxy-4a-methyl-6-oxo-1,2,3,4,4a,5,6,7-octahydro-naphthalene-1-carboxylic acid methyl ester 
• 105631-41-2 (4'aS,5'R,8'aR)-8'a-Methyl-octahydro-spiro[[1,3]dioxolane-2,2'-naphthalene]-5'-carboxylic acid methyl ester 
• 105631-43-4 (4'aS,8'aR)-8'a-Methyl-5'-methylene-octahydro-spiro[[1,3]dioxolane-2,2'-naphthalene] 
• 105631-42-3 ((4'aS,5'R,8'aR)-8'a-Methyl-octahydro-spiro[[1,3]dioxolane-2,2'-naphthalen]-5'-yl)-methanol 
• 74064-03-2 (3aR,4aS,8aR,9aS)-3,8a-Dimethyl-5-methylene-3-phenylsulfanyl-decahydro-naphtho[2,3-b]furan-2-one 
• 600151-49-3 6-methoxy-4a-methyl-1,2,3,4,4a,5,8,8a-octahydronaphthalen-1-one 
• 162657-45-6 6-methoxy-4a-methyl-1-(trimethylsilyloxy)-2,3,4,4a,5,8-hexahydronaphthalene 
• 3241-65-4 (+/-)-8a-methyl-5-methylene-octahydro-naphthalen-2(1H)-one 
• 1201-61-2 1,2,3,4,5,8-hexahydro-1-hydroxy-6-methoxynaphthalene 
• 2844-80-6 1,2,3,4,5,8-hexahydro-1-oxo-6-methoxynaphthalene 

Downstream Products

• 3241-66-5 4aα,5,6,7,8,8a,9,9aβ-octahydro-3-methyl-5-methylenenaphtho<2,3-b>furan-2(4H)-one 
• 94204-13-4 9a-hydroxy-3,8a-dimethyl-5-methylene-4a,5,6,7,8,8a,9,9a-octahydro-4H-naphtho[2,3-b]furan-2-one 
• 182426-37-5 (+/-)-3,8a,3',8'a-tetramethyl-5,5'-dimethylene-4,4a,5,6,7,8,8a,9,4',4'a,5',6',7',8',8'a,9'-hexadecahydro-[9a,9'a]bi[naphtho[2,3-b]furanyl]-2,2'-dione 
• 182426-37-5 3,8a,3',8'a-tetramethyl-5,5'-dimethylene-4,4a,5,6,7,8,8a,9,4',4'a,5',6',7',8',8'a,9'-hexadecahydro[9a,9'a]bi[naphtho[2,3-b]furanyl]-2,2'-dione 
• 182426-37-5 (+/-)-3,8a,3',8'a-tetramethyl-5,5'-dimethylene-4,4a,5,6,7,8,8a,9,4',4'a,5',6',7',8',8'a,9'-hexadecahydro-[9a,9'a]bi[naphtho[2,3-b]furanyl]-2,2'-dione 
• 6466-81-5 3,8a-dimethyl-5-methylene-4a,5,6,7,8,8a-hexahydro-4H-naphtho[2,3-b]furan-2-one 

Relevant articles and documents

Dimerization of butenolide structures. A biomimetic approach to the dimeric sesquiterpene lactones (±)-biatractylolide and (±)- biepiasterolide

The biomimetic synthesis of the bisesquiterpene lactones (±)-biatractylolide 1 and (±)-biepiasterolide 2 via dimerization of the captodative stabilized radical 8 is reported. Atractylon 7 has also been shown to be a possible intermediate during the biosynthesis of biatractylolide 1, biepiasterolide 2, atractylolide 3, and hydroxyatractylolide 4.

TOTAL SYNTHESIS OF (+/-)-ATRACTYLON AND (+/-)-LINDESTRENE

The total synthesis of the eudesmane furanosesquiterpenes (+/-)-atractylon (1) and (+/-)-lindestrene (2) is described.Both 1 and 2 were synthesized via the methyl xanthate intermediate (10).