349149-07-1

Basic information

• Product Name: S-2,2'-bis(methoxymethoxy)-[1,1'-Binaphthalene]-3-carboxaldehyde
• Synonyms: S-2,2'-bis(methoxymethoxy)-[1,1'-Binaphthalene]-3-carboxaldehyde;(1S)-2,2'-Bis(methoxymethoxy)-[1,1'-binaphthalene]-3- carboxaldehyde
• CAS NO: 349149-07-1
• Molecular Formula: C₂₅H₂₂O₅
• Molecular Weight: 402.43918
• Mol File: 349149-07-1.mol
• Article Data: 8

Chemical Properties

• Appearance: /
• CAS DataBase Reference: S-2,2'-bis(methoxymethoxy)-[1,1'-Binaphthalene]-3-carboxaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: S-2,2'-bis(methoxymethoxy)-[1,1'-Binaphthalene]-3-carboxaldehyde(349149-07-1)
• EPA Substance Registry System: S-2,2'-bis(methoxymethoxy)-[1,1'-Binaphthalene]-3-carboxaldehyde(349149-07-1)

Safety Data

• Hazardous Substances Data: 349149-07-1(Hazardous Substances Data)

Upstream product

• 602-09-5 1,1'-bi-2-naphthol 
• 68-12-2 N,N-dimethyl-formamide 
• 173831-50-0 rac-2,2'-bis-(methoxymethoxy)-1,1'-binaphthalene 

Downstream Products

• 12083-24-8 tricarbonyl(η(6)-toluene)chromium 
• 265116-85-6 3,3''-(oxydimethylene)-di-1,1'-bi-2-naphthol 
• 345659-34-9 (R)-2,2'-dihydroxy-[1,1']-binaphthyl-3-carbaldehyde 

Relevant articles and documents

Compound boranil based on bi bisnaphthol of the framework and its preparation and use

The invention provides a series of Boranil compounds based on 1,1'-binaphthol parents, a preparation method of the compounds, and application of the compounds on detection of fluorine ions. The compounds meet one of the following general formulas, X is on

A simple complex: ‘on–off–on’ colorimetric and ratiometric fluorescence response towards fluoride ions and its solid state optical properties

A simple 1,1′-bi-2-naphthol (1,1′-BINOL) boron complex has been rationally designed and synthesized, the structure of which was confirmed by single crystal X-ray diffraction analysis. Furthermore, the complex exhibited turn-on fluorescence for fluoride ions with high selectivity and sensitivity. The recognition mechanism for promoting was determined by 1H, 19F and 11B NMR titrations, which indicated that both the photo-induced electron-transfer (PET) and the intramolecular charge transfer (ICT) effects were functionalized. In addition, the complex showed strong solid-state fluorescence, and the emission spectrum and quantum efficiency (ΦF) of the solid powders were also measured.

CATALYST FOR ASYMMETRIC SYNTHESIS, LIGAND FOR USE THEREIN, AND PROCESS FOR PRODUCING OPTICALLY ACTIVE COMPOUND THROUGH ASYMMETRIC SYNTHESIS REACTION USING THEM

Compounds represented by the following general formula (1a) or (1b). A complex comprising a center metal of rhodium and a compound represented by the following general formula (1a) or (1b) as a ligand. A catalyst for optically active beta-substituted carbonyl compound synthesis and catalyst for asymmetric 1, 2 addition reaction being composed of the complex. A method of production of an optically active beta-aryl compound from an alpha, beta-unsaturated compound and an aryl-boronic acid derivative and method of production of an optically active aryl alcohol compound from an aldehyde compound and aryl boronic acid derivatives using the catalyst. A complex comprising a center metal of palladium and a compound represented by the following general formula (1a) or (1b) as a ligand. A catalyst for asymmetric allylic substitution reaction being composed of the complex. A method of production of an optically active dialkyl (1,3-disubstituted propeny)malonate compound from a 1,3- disubstituted ally acetate compound and a dialkyl malonate and method of production of an optically active allylamine compound from a 1,3-disubstituted ally acetate compound and an amine compound. The compounds have not only the versatility of being usable in the synthesis of wide-ranging optically active aryl compounds but also the selectivity and reactivity permitting synthesis with high yield within a short period of time under industrially advantageous mild conditions.