35044-00-9

Basic information

• Product Name: Cyclohexene, 3,6-dibromo-
• Synonyms: 3,6-dibromo-cyclohexene;Cyclohexene,3,6-dibromo;3,6-Dibrom-1-cyclohexen;3,6-dibromo-1-cyclohexene;3,6-Dibrom-cyclohexen
• CAS NO: 35044-00-9
• Molecular Formula: C6H8Br2
• Molecular Weight: 239.938
• Mol File: 35044-00-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexene, 3,6-dibromo-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexene, 3,6-dibromo-(35044-00-9)
• EPA Substance Registry System: Cyclohexene, 3,6-dibromo-(35044-00-9)

Safety Data

• Hazardous Substances Data: 35044-00-9(Hazardous Substances Data)

Upstream product

• 56-23-5 tetrachloromethane 
• 128-08-5 N-Bromosuccinimide 
• 110-83-8 cyclohexene 
• 94-36-0 dibenzoyl peroxide 
• 121-44-8 triethylamine 
• 88-89-1 2,4,6-Trinitrophenol 
• 7732-18-5 water 
• 1165952-91-9 cyclohexa-1,3-diene 
• 67-63-0 isopropyl alcohol 
• 64-17-5 ethanol 
• 71-23-8 propan-1-ol 
• 67-56-1 methanol 
• 1521-51-3 rac-3-bromocyclohexene 

Downstream Products

• 71-43-2 benzene 
• 91147-88-5 C₂₀H₂₂O₂ 
• 91147-90-9 C₂₀H₂₂O₂ 
• 91147-89-6 C₁₈H₁₆Cl₂O₂ 
• 113260-87-0 3,6-bis(N-methylanilino)cyclohexene 
• 91160-51-9 C₁₈H₁₄Cl₄O₂ 
• 57160-05-1 1,2,3,4-tetrabromocyclohexane 
• 10035-10-6 hydrogen bromide 
• 53762-85-9 (1S,4R)-Cyclohex-2-ene-1,4-diol 
• 91147-91-0 4-Methyl-2-(6-p-tolyloxy-cyclohex-2-enyl)-phenol 
• 91147-96-5 2,4-<3'-p-cresoxypropano>-3-bromo-6-methylchroman 
• 91147-92-1 4-Chloro-2-[6-(4-chloro-phenoxy)-cyclohex-2-enyl]-phenol 
• 91160-52-0 2,4-<3'-p-cresoxypropano>-3-chloromercuri-6-methylchroman 
• 91147-93-2 2-<6'-p-cresoxy-2'-cyclohexenyl>-p-cresol acetate 

Relevant articles and documents

Regio- and Stereo-Controlled Alkoxyiodination of 1,3-Diene Using Iodine-Cerium(IV) Ammonium Nitrate

Reaction of 1,3-cycloalkadienes (cyclopentadiene, cyclohexadiene, and cycloheptadiene) with iodine-cerium(IV) ammonium nitrate in alcohols, gave the corresponding regiospecific trans-2-alkoxy-1-iodo compounds as major products accompanied with 1,4-dialkoxy compounds as by-products.In the case of CH3CN-H2O as solvent, trans-iodohydrins were obtained.Thus the reaction of cyclic and acyclic i671,3-diene derivatives using this synthetic method afforded the 1,2-addition alkoxyiodo compounds preferentially.

Studies on Rearrangement of 3,6-Diaryloxycyclohexenes

Claisen rearrangement of 3,6-diaryloxycyclohexenes furnish a viscous oil which gives positive ferric chloride test and a solid acetyl derivative (IV) indicating the phenolic nature of th rearranged product.The acetyl derivative (IV) consumes one mol of bromine to give a dibromo derivative (V) which undergoes a base-catalysed cyclisation to give 2,4-(3'-p-cresoxypropano)-3-bromo-6-methylchroman (VII).