35122-84-0

Basic information

• Product Name: Benzenamine, 3-methoxy-N,N,5-trimethyl-
• CAS NO: 35122-84-0
• Molecular Formula: C10H15NO
• Molecular Weight: 165.235
• Mol File: 35122-84-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenamine, 3-methoxy-N,N,5-trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 3-methoxy-N,N,5-trimethyl-(35122-84-0)
• EPA Substance Registry System: Benzenamine, 3-methoxy-N,N,5-trimethyl-(35122-84-0)

Safety Data

• Hazardous Substances Data: 35122-84-0(Hazardous Substances Data)

Upstream product

• 672-89-9 4-methoxy-6-methyl-2H-pyran-2-one 
• 867-89-0 1-dimethylamino-1-methoxyethylene 
• 512-56-1 trimethyl phosphite 
• 66584-31-4 3-methoxy-5-methylphenylamine 

Relevant articles and documents

Syntheses of Highly Substituted Benzenes via Diels-Alder Reactions with 2H-Pyran-2-ones

The 2H-pyran-2-ones (α-pyrones) 1 react as dienes in Diels-Alder reactions with acetylene derivatives.The primarely formed cycloadducts immediately aromatize to benzenes by CO2 elimination.Thus, methyl acetylenedicarboxylate (2a) gives dimethyl phthalates 3, and methyl acetylenediphosphonate (2b) gives dimethyl 1,2-phenylenediphosphonates 8.The reactions of 1-(dimethylamino)-1-methoxyethene (9) with 1 regioselectively produce N,N-dimethylanilines 10 and isomeric homophthalate derivatives 12.Naphthoquinones 14 could be generated from 1,4-benzoquinone (13) and 1 in the presence of acetic anhydride and Pd/C.Hydroxy-2H-pyran-2-ones 4 react via their trimethylsilyl ether 6 analogously with 2a to give dimethyl (trimethylsiloxy)phthalates 7 which are easily converted to phenols 5 by acid-catalyzed hydrolysis.