35129-66-9Relevant articles and documents
Urea-Oxaziridines
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Paragraph 0122-0124, (2021/05/28)
Chemoselective conjugation is achieved through redox reactivity by reacting an N-transfer oxidant with a thioether substrate in a redox reaction in an aqueous environment to form a conjugation product. In embodiments, Redox-Activated Chemical Tagging (ReACT) strategies for methionine-based protein functionalization. Oxaziridine (Ox) compounds serve as oxidant-mediated reagents for direct functionalization by converting methionine to the corresponding sulfimide conjugation product.
Exploiting the Nucleophilicity of N-H Imines: Synthesis of Enamides from Alkyl Azides and Acid Anhydrides
Han, Junghoon,Jeon, Mina,Pak, Han Kyu,Rhee, Young Ho,Park, Jaiwook
, p. 2769 - 2774 (2016/02/18)
The nucleophilicity of N-unsubstituted imines, which were generated from alkyl azides by a ruthenium-catalyzed reaction, was investigated in the reaction with acid anhydrides. The initial products were N-acylimines, which isomerized to the corresponding e
New stable N-H oxaziridines - Synthesis and reactivity
Blanc, Sylvain,Bordogna, Celine A. C.,Buckley, Benjamin R.,Elsegood, Mark R. J.,Bulman Page, Philip C.
experimental part, p. 882 - 889 (2010/04/05)
A number of stable new N-H oxaziridines have been designed and prepared, and their reactivity as electrophilic sources of nitrogen investigated. 3-tert-Butyl-3-phenyloxaz-ridine is the most efficient and stable and has potential for use as a general reagent for this purpose.
