35192-73-5 Usage
Description
1-Nonen-4-ol is an organic compound with a nine-carbon chain and a hydroxyl group at the fourth carbon atom. It is a colorless to pale yellow liquid with a distinctive odor and is soluble in water and various organic solvents. 1-Nonen-4-ol is known for its versatile chemical properties and potential applications in different industries.
Uses
1-Nonen-4-ol is used as a reagent in the chemical industry for MnO2-promoted chemoand regioselective preparation of β-hydroxyalkyl and Me ketones. This application is particularly valuable in the synthesis of complex organic molecules and pharmaceutical compounds, as it allows for the selective formation of specific products with high efficiency and minimal side reactions.
Used in Chemical Synthesis:
1-Nonen-4-ol is used as a building block for the synthesis of various organic compounds, including pharmaceuticals, agrochemicals, and specialty chemicals. Its unique structure and reactivity make it a valuable intermediate in the development of new molecules with specific properties and applications.
Used in Flavor and Fragrance Industry:
1-Nonen-4-ol is used as a component in the creation of natural and synthetic flavors and fragrances. Its distinct odor and compatibility with other fragrance ingredients make it a useful addition to the development of new scents for the perfume, cosmetics, and food industries.
Used in Research and Development:
1-Nonen-4-ol is utilized as a research compound in academic and industrial laboratories. Its unique properties and reactivity make it an interesting subject for studying various chemical reactions and processes, contributing to the advancement of chemical knowledge and the development of new technologies.
Synthesis Reference(s)
Journal of the American Chemical Society, 110, p. 4473, 1988 DOI: 10.1021/ja00221a091Tetrahedron Letters, 29, p. 3563, 1988 DOI: 10.1016/0040-4039(88)85293-6
Check Digit Verification of cas no
The CAS Registry Mumber 35192-73-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,5,1,9 and 2 respectively; the second part has 2 digits, 7 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 35192-73:
(7*3)+(6*5)+(5*1)+(4*9)+(3*2)+(2*7)+(1*3)=115
115 % 10 = 5
So 35192-73-5 is a valid CAS Registry Number.
InChI:InChI=1/C9H18O/c1-3-5-6-8-9(10)7-4-2/h4,9-10H,2-3,5-8H2,1H3/t9-/m0/s1
35192-73-5Relevant articles and documents
Synthesis of Enantiopure Homoallylic Alcohols and Ethers by Diastereoselective Allylation of Aldehydes
Tietze, Lutz F.,Schiemann, Kai,Wegner, Christoph,Wulff, Christian
, p. 1164 - 1172 (2007/10/03)
Enantiopure homoallylic alcohols 5, which are important building blocks in organic synthesis, are obtained with an ee of greater than 99percent and a yield of 75-95percent by cleavage of the secondary homoallylic ethers 4 using sodium in liquid ammonia.The ethers 4 are formed with excellent diastereoselectivity and in 52-89percent yield by treatment of the aldehydes 1 with the trimethylsilyl ether of N-trifluoroacetylnorpseudoephedrine (2) in the presence of a catalytic amount of TMS triflate or TMS borontriflate, followed by addition of allylsilane 3.Nearly all achiral aliphatic aldehydes employed gave a diastereoselectivity of over 99:1.With the chiral aldehydes 24, the difference between matched and mismatched pairs was low; this reveals that there is strong reagent control.- Keywords: allylations; allylsilanes; double stereodifferentiation; ephedrine; homoallylic alcohols
