35228-40-1

Basic information

• Product Name: Pentanethioamide, N-(4-methoxyphenyl)-
• CAS NO: 35228-40-1
• Molecular Formula: C12H17NOS
• Molecular Weight: 223.339
• Mol File: 35228-40-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Pentanethioamide, N-(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Pentanethioamide, N-(4-methoxyphenyl)-(35228-40-1)
• EPA Substance Registry System: Pentanethioamide, N-(4-methoxyphenyl)-(35228-40-1)

Safety Data

• Hazardous Substances Data: 35228-40-1(Hazardous Substances Data)

Upstream product

• 693-03-8 n-butyl magnesium bromide 
• 2284-20-0 4-Methoxyphenyl isothiocyanate 
• 73644-87-8 N-(4-methoxyphenyl)pentanamide 
• 638-29-9 n-valeryl chloride 
• 104-94-9 4-methoxy-aniline 
• 75-15-0 carbon disulfide 

Downstream Products

• 882-42-8 N-(4-methoxy-phenyl)-N-pentyl-amine 

Relevant articles and documents

Lewis Base-Boryl Radicals Enabled the Desulfurizative Reduction and Annulation of Thioamides

A new protocol for radical transformations of thioamides promoted by Lewis base-boryl radicals is reported. The desulfurizative reduction to access organic amines was enabled utilizing 4-dimethylaminopyridine-BH3 as the boryl radical precursor and PhSH as the polarity reversal catalyst. Alternatively, the chain process for unsaturated thioamides was switched to an annulation reaction using N-heterocyclic carbene-BH3 as the boryl radical precursor and sterically bulky Ph3CSH as the catalyst, allowing for the construction of N-heterocyclic and carbocyclic skeletons.