35305-17-0Relevant articles and documents
Lewis Acid Activation of the Ferrous Heme-NO Fragment toward the N-N Coupling Reaction with NO to Generate N2O
Abucayon, Erwin G.,Khade, Rahul L.,Powell, Douglas R.,Zhang, Yong,Richter-Addo, George B.
, p. 4204 - 4207 (2018)
Bacterial NO reductase (bacNOR) enzymes utilize a heme/non-heme active site to couple two NO molecules to N2O. We show that BF3 coordination to the nitrosyl O-atom in (OEP)Fe(NO) activates it toward N-N bond formation with NO to generate N2O. 15N-isotopic labeling reveals a reversible nitrosyl exchange reaction and follow-up N-O bond cleavage in the N2O formation step. Other Lewis acids (B(C6F5)3 and K+) also promote the NO coupling reaction with (OEP)Fe(NO). These results, complemented by DFT calculations, provide experimental support for the cis:b3 pathway in bacNOR.
Nucleophilic addition reactions of the nitroprusside ion - The case of O-methylhydroxylamine
Gutierrez, Maria M.,Olabe, Jose A.,Amorebieta, Valentin T.
, p. 4433 - 4438 (2013/01/14)
The kinetics of the reaction between aqueous solutions of [Fe(CN) 5NO]2- and NH2OCH3 has been studied by means of UV/Vis spectroscopy and complementary solution techniques, FTIR/ATR spectroscopy, mass spectromet
Stabilization of ammonium dinitramide in the liquid phase
Andreev,Anikin,Ivanov,Krylov,Pak
, p. 1974 - 1976 (2007/10/03)
The kinetics of accumulation of the main products of thermal decomposition of ammonium dinitramide in the melt was investigated. The isotope composition of nitrogen-containing gases evolved by the decomposition of 15NH4N(NO2/su
