35357-34-7Relevant articles and documents
Total synthesis of (±)-antroquinonol D
Sulake, Rohidas S.,Jiang, Yan-Feng,Lin, Hsiao-Han,Chen, Chinpiao
, p. 10820 - 10828 (2014)
Total synthesis of (±)-antroquinonol D, which is isolated from very expensive and rarely found Antrodia camphorata and which has potential anticancer properties, was achieved from 4-methoxyphenol. In addition, a Michael addition to dimethoxy cyclohexadien
Thermal and Photochemical Rearrangements of Cyclopropyl Ethers of p-Quinols. Competing Reaction Pathways Leading to Five- and Six-Membered Ring Spirocyclic Ketones
Biggs, Timothy N.,Swenton, John S.
, p. 5568 - 5573 (1992)
Cyclopropyl ethers of p-quinols were prepared by reaction of 3''-methylenedispirocyclohexadiene-4',1''(3''H)-isobenzofuran> and the associated ketone with ethyl diazoacetate/rhodium(II) acetate and diethylzinc/methylene iodide, re
Synthesis of o-chlorophenols via an unexpected nucleophilic chlorination of quinone monoketals mediated by N,N′-dimethylhydrazine dihydrochloride
Yin, Zhiwei,Zhang, Jinzhu,Wu, Jing,Green, Riana,Li, Sihan,Zheng, Shengping
supporting information, p. 2854 - 2858 (2014/05/06)
An unexpected nucleophilic chlorination of a quinone monoketal while carrying out a pyrazolidine synthesis has led to a general preparation of multisubstituted phenols. The products are obtained in good to high yields under mild conditions. The bridged pyrazolidines that were the original targets are obtained in the presence of a protic solvent. This journal is the Partner Organisations 2014.
A total synthesis of millingtonine a
Wegner, Jens,Ley, Steven V.,Kirschning, Andreas,Hansen, Anne-Lene,Montenegro Garcia, Javier,Baxendale, Ian R.
supporting information; experimental part, p. 696 - 699 (2012/04/17)
A total synthesis of millingtonine A, a diglycosylated alkaloid, has been accomplished. Millingtonine A possesses a unique racemic tricyclic core structure not known from any other natural or synthetic source until now. The synthesis features a key bond-f