355012-44-1Relevant articles and documents
Catalytic diboration of unsaturated molecules with platinum(0)-NHC: Selective synthesis of 1,2-dihydroxysulfones
Lillo, Vanesa,Mata, Jose,Ramirez, Jesus,Peris, Eduardo,Fernandez, Elena
, p. 5829 - 5831 (2006)
Readily available N-heterocyclic platinum complexes provide active catalytic species for 1,2-diboration and anticipate a wide range of applications in alkenes and alkynes. Unprecedented catalytic B - B addition of heteroatom-containing sub-strates provided high selectivity into organosulfur - diboronate esters. Their in situ basic oxidation afforded the desired 1,2-dihydroxysulfones in high yields.