35505-99-8

Basic information

• Product Name: (E) 3-(4-cyanophenyl)-1-phenyl-propene
• Synonyms: (E) 3-(4-cyanophenyl)-1-phenyl-propene
• CAS NO: 35505-99-8
• Molecular Weight: 219.286
• Mol File: 35505-99-8.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (E) 3-(4-cyanophenyl)-1-phenyl-propene(CAS DataBase Reference)
• NIST Chemistry Reference: (E) 3-(4-cyanophenyl)-1-phenyl-propene(35505-99-8)
• EPA Substance Registry System: (E) 3-(4-cyanophenyl)-1-phenyl-propene(35505-99-8)

Safety Data

• Hazardous Substances Data: 35505-99-8(Hazardous Substances Data)

Upstream product

• 21040-45-9 Cinnamyl acetate 
• 623-00-7 4-bromobenzenecarbonitrile 
• 6783-05-7 trans-2-phenylvinylboronic acid 
• 16473-21-5 1-cyano-4-(fluoromethyl)benzene 
• 300-57-2 allylbenzene 
• 126747-14-6 4-cyanophenylboronic acid 
• 4363-35-3 Dihydroxy-styryl-boran 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 

Relevant articles and documents

Palladium(0)-catalyzed direct cross-coupling reaction of allyl alcohols with aryl- and vinyl-boronic acids

Allyl alcohols can be directly used for the palladium-catalyzed allylation of aryl- and vinyl-boronic acids without the aid of a base.

Cu-Catalyzed Oxidative Allylic C-H Arylation of Inexpensive Alkenes with (Hetero)Aryl Boronic Acids

Herein, we present a regioselective Cu-catalyzed oxidative allylic C(sp3)-H arylation by radical relay using a broad range of heteroaryl boronic acids with inexpensive and readily available unactivated terminal and internal olefins. This C(sp2)-C(sp3) allyl coupling has the advantage of using cheap, abundant, and nontoxic Cu2O without the need to use prefunctionalized alkenes, thus offering an alternative method to allylic arylation reactions that employ more traditional coupling partners with preinstalled leaving groups (LGs) at the allylic position.

Palladium catalyzed Suzuki cross-coupling of benzyltrimethylammonium salts via C-N bond cleavage

A palladium catalyzed Suzuki cross-coupling for construction of Csp3-Csp2 bond via Csp3-N bond activation of benzyltrimethyl-ammonium salt is described. This reaction not only offered a highly efficient approach to diarylmethanes but also paved the way for the application of benzyltrimethylammonium salts in the palladium catalyzed cross coupling reactions.