35525-50-9

Basic information

• Product Name: bis(tri-n-butylstannyl) ethane dithiolate
• Synonyms: bis(tri-n-butylstannyl) ethane dithiolate
• CAS NO: 35525-50-9
• Molecular Weight: 672.299
• Mol File: 35525-50-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis(tri-n-butylstannyl) ethane dithiolate(CAS DataBase Reference)
• NIST Chemistry Reference: bis(tri-n-butylstannyl) ethane dithiolate(35525-50-9)
• EPA Substance Registry System: bis(tri-n-butylstannyl) ethane dithiolate(35525-50-9)

Safety Data

• Hazardous Substances Data: 35525-50-9(Hazardous Substances Data)

Upstream product

• 177-16-2 1,4-dithiaspiro[4.5]decane 
• 688-73-3 tri-n-butyl-tin hydride 

Relevant articles and documents

Tri-n-butyltin Hydride: A Selective Reducing Agent for 1,3-Dithiolanes

Tri-n-butyltin hydride has been found to be an effective and selective agent for complete or partial desulfurization of 1,3 dithiolanes 1.The reaction of 1 with 4 equiv of tri-n-butyltin hydride in the presence of 2,2'-azobis(isobutyronitrile) results in complete desulfurization, giving hydrocarbons 2 in good yield, ethane and bis(tri-n-butyltin) sulfide.Two equivalents of hydride specifically cleave the two geminal C-S bonds in 1 to give hydrocarbons 2 and bis(tri-n-butylstannyl) ethanedithiolate.One equivalent of tri-n-butyltin hydride reduces 1 quantitatively to the β-ethyl tri-n-butyltin sulfides 11.