35546-71-5Relevant articles and documents
Synthesis, crystal structures, fluorescence, electrochemiluminescent properties, and Hirshfeld surface analysis of four Cu/Mn Schiff-basecomplexes
Zeng, Yumei,Zhang, Haiyang,Zhang, Yujie,Ji, Fanghua,Liang, Jinlu,Zhang, Shuhua
, (2020)
Four new complexes [Cu(L1)2]n (1), [Mn(L1)2]n (2), [Cu(L2)2]n (3), [Mn(L2)2]n (4, HL1 = 2-(((4H-1,2,4-triazol-4-yl)imino)methyl)-4,6-dichlorophenol; HL2 = 2-(((4H-1,2,4-triazol-4-yl)imino)methyl)-4,6-dibromophenol) were synthesized by microreaction bottle method. Complexes 1 and 3 and 2 and 4 are isomorphous heterostructures having the same molecular structure. The structures of 1–4 were characterized using single X-ray diffraction, Fourier-transform infrared spectroscopy, powder X-ray diffraction, and thermogravimetric analysis, and their potential applications were analyzed by detecting their fluorescence and electrochemical luminescence (ECL). Hirshfeld surface analysis indicates that X···H (X = Br, Cl) interactions play a crucial role in stabilizing the self-assembly process of 1–4, which show highly intense ECL in N,N-dimethylformamide solution and high thermal stability.