35602-33-6Relevant articles and documents
Regioselective oxidation of azidodiols, bromodiols and triol derivatives by dimethyldioxirane
Bovicelli, Paolo,Truppa, Danilo,Sanetti, Anna,Bernini, Roberta,Lupattelli, Paolo
, p. 14301 - 14314 (2007/10/03)
Azidodiols, bromodiols and triol derivatives were regioselectively monooxidised to the corresponding ketols using dimethyldioxirane. This regioselectivity is essentially determined by dipolar functionalities close to the potential reactive carbinol. These results make the reactivity of polyols with dimethyldioxirane highly predictable.