35657-16-0

Basic information

• Product Name: m-(Chloromethylthio)toluene
• Synonyms: 1-Chloromethylthio-3-methylbenzene;m-(Chloromethylthio)toluene
• CAS NO: 35657-16-0
• Molecular Formula: C₈H₉ClS
• Molecular Weight: 0
• Mol File: 35657-16-0.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: m-(Chloromethylthio)toluene(CAS DataBase Reference)
• NIST Chemistry Reference: m-(Chloromethylthio)toluene(35657-16-0)
• EPA Substance Registry System: m-(Chloromethylthio)toluene(35657-16-0)

Safety Data

• Hazardous Substances Data: 35657-16-0(Hazardous Substances Data)

Upstream product

• 1899-93-0 3-methylphenylsulfonyl chloride 
• 74-97-5 chlorobromomethane 
• 108-40-7 toluene-3-thiol 
• 50-00-0 formaldehyd 
• 4886-77-5 3-methylthioanisole 

Downstream Products

• 83768-11-0 5-chloro-1-(3-tolylsulfenyl)methyl-2(1H)-pyrimidinone 
• 119561-40-9 (m-tolylthio)methyl 2-chloro-6-(4,6-dimethoxypyrimidin-2-yl)oxy benzoate 
• 111621-35-3 (+/-)-Tochuinyl acetate 
• 51941-57-2 (1R^*,2S^*)-1,2-Dimethyl-2-(4-methylphenyl)cyclopentanemethanol 
• 130398-94-6 (1R*,2S*)1,2-Dimethyl-1-(p-tolyl)cyclopentane 
• 4608-43-9 2,3-dimethyl-3-(4-methylphenyl)-cyclopentanol 
• 4608-44-0 2,3-dimethyl-3-(p-tolyl)cyclopentan-1-one 
• 16982-00-6 1-(1,2,2-trimethylcyclopentyl)-4-methylbenzene 
• 83768-14-3 5-bromo-2-(3-tolylsulfenyl)methyloxypyrimidine 
• 83768-13-2 5-bromo-1-(3-tolylsulfenyl)methyl-2(1H)-pyrimidinone 
• 83768-12-1 5-chloro-2-(3-tolylsulfenyl)methyloxypyrimidine 

Relevant articles and documents

Synthesis of thiochromans by means of a [4+ + 2] polar cycloaddition of m-tolylthiomethyl chloride with substituted alkenes: A simple synthesis of (±)-cuparene and related sesquiterpenoids

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SYNTHESIS AND CONFIGURATIONAL STUDIES OF ARYL CYCLOPROPYL SULFONES

The cycloaddition of arylthiocarbenes to styrene gave stereospecifically cis-1-(arylthio)-2-phenylcyclopropanes, which were subsequently oxidized to the corresponding sulfones.The cyclopropanation of α,β-unsaturated sulfones with dimethylsulfonium methylide yielded stereoselectively trans-1-(arylsulfonyl)-2-arylcyclopropanes.The configurational assignments of these compounds have been arrived at on the basis of IR and PMR spectral data.Chemical shifts for ring protons and other substituents reveal that all the substituents tend to cause protons cis to them to appear at higher fields than those trans to them.This has been used as a criterion to distinguish between cis and trans aryl cyclopropyl sulfones.