35736-66-4Relevant articles and documents
Efficient photooxygenation of olefins by a C60 derivative bearing an organofluorine tail
Nagashima, Hideo,Hosoda, Koji,Abe, Tomoaki,Iwamatsu, Shoichi,Sonoda, Takaaki
, p. 469 - 470 (2007/10/03)
A C60 derivative bearing an organofluorine tail through the dimethylsilyl moiety (1) was proved to be an efficient photosensitizer in C6F6. Photooxygenation of olefins or dienes was accomplished by catalysis of 1 (0.5 - 1.5 mo1%) at room temperature under an oxygen atmosphere.
Biotransformation Products of (5R)-(+)-Pulegone and (2S,5R)-(-)-Menthone Produced by Cultured Cells of Catharanthus roseus
Williams, Howard J.,Moyna, Guillermo,Scott, A. Ian,Hamada, Hiroki,Lwin, War War,Tanaka, Toshinori,Furuya, Tsutomu
, p. 838 - 840 (2007/10/03)
Catharanthus roseus cultured cells produce several new oxidized products from (5R)-(+)-pulegone and (2S, 5R)-(-)-menthone, in some of which a double bond migration has occurred. Products were identified using NMR and mass spectrometry. The pleasant fragrances of some of the products suggest possible use as perfumery agents.
Biotransformation of terpenic compounds by fungi. I. Metabolism of R-(+)-pulegone
Ismaili-Alaoui,Benjilali,Buisson,Azerad
, p. 2349 - 2352 (2007/10/02)
R-(+)-Pulegone 1 is converted by several fungal strains to new regioselectively hydroxylated compounds. Epoxidation of the double bond does not seem to be responsible for the main observed hydroxylation pattern.