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35835-94-0

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35835-94-0 Usage

General Description

Ethyltriphenylphosphonium acetate is a chemical compound that consists of a triphenylphosphonium cation and an acetate anion. It is commonly used as a precursor in organic synthesis and pharmaceutical research. Ethyltriphenylphosphonium acetate is known for its ability to act as a strong base and nucleophile, making it useful in the formation of carbon-carbon and carbon-heteroatom bonds. It has been studied for its potential application in the synthesis of biologically active compounds and as a reagent in organic reactions. Additionally, its structure and reactivity make it a useful reagent in the synthesis of various organic compounds, making it an important chemical in the field of organic chemistry.

Check Digit Verification of cas no

The CAS Registry Mumber 35835-94-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,5,8,3 and 5 respectively; the second part has 2 digits, 9 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 35835-94:
(7*3)+(6*5)+(5*8)+(4*3)+(3*5)+(2*9)+(1*4)=140
140 % 10 = 0
So 35835-94-0 is a valid CAS Registry Number.
InChI:InChI=1/C20H20P.C2H4O2/c1-2-21(18-12-6-3-7-13-18,19-14-8-4-9-15-19)20-16-10-5-11-17-20;1-2(3)4/h3-17H,2H2,1H3;1H3,(H,3,4)/q+1;/p-1

35835-94-0 Well-known Company Product Price

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  • Alfa Aesar

  • (17426)  Ethyltriphenylphosphonium acetate, 70% in methanol   

  • 35835-94-0

  • 100g

  • 459.0CNY

  • Detail
  • Alfa Aesar

  • (17426)  Ethyltriphenylphosphonium acetate, 70% in methanol   

  • 35835-94-0

  • 500g

  • 1550.0CNY

  • Detail
  • Alfa Aesar

  • (17426)  Ethyltriphenylphosphonium acetate, 70% in methanol   

  • 35835-94-0

  • 2.5kg

  • 3178.0CNY

  • Detail

35835-94-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name ethyl(triphenyl)phosphanium,acetate

1.2 Other means of identification

Product number -
Other names Ethyltriphenylphosphonium Acetate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:35835-94-0 SDS

35835-94-0Synthetic route

potassium acetate
127-08-2

potassium acetate

ethyltriphenylphosphonium chloride
896-33-3

ethyltriphenylphosphonium chloride

ethyltriphenylphosphonium acetate
35835-94-0

ethyltriphenylphosphonium acetate

Conditions
ConditionsYield
In ethanol at 20℃; for 16.33h; Schlenk technique; Inert atmosphere;94%
ferrocenecarboxaldehyde
12093-10-6

ferrocenecarboxaldehyde

ethyltriphenylphosphonium acetate
35835-94-0

ethyltriphenylphosphonium acetate

A

trans-1-ferrocenyl-1-propene

trans-1-ferrocenyl-1-propene

B

(Z)-1-prop-1-enylferrocene

(Z)-1-prop-1-enylferrocene

Conditions
ConditionsYield
In tetrahydrofuran at 50℃; for 24h; Wittig Olefination; Schlenk technique; Inert atmosphere; Overall yield = 66 percent; Overall yield = 30 mg;A n/a
B n/a
ethyltriphenylphosphonium acetate
35835-94-0

ethyltriphenylphosphonium acetate

ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

A

(Z)-1-bromo-2-(2-methylethenyl)benzene
70968-46-6, 74532-86-8, 70913-21-2

(Z)-1-bromo-2-(2-methylethenyl)benzene

B

(E)-1-bromo-2-(2-methylethenyl)benzene
70913-21-2, 74532-86-8, 70968-46-6

(E)-1-bromo-2-(2-methylethenyl)benzene

Conditions
ConditionsYield
In tetrahydrofuran at 40℃; for 24h; Wittig Olefination; Schlenk technique; Inert atmosphere; Overall yield = 79 percent; Overall yield = 31 mg;A n/a
B n/a
ethyltriphenylphosphonium acetate
35835-94-0

ethyltriphenylphosphonium acetate

2-nitro-benzaldehyde
552-89-6

2-nitro-benzaldehyde

A

(E)-1-nitro-2-(prop-1-en-1-yl)benzene
4036-19-5

(E)-1-nitro-2-(prop-1-en-1-yl)benzene

B

1-nitro-2-(prop-1-en-1-yl)benzene

1-nitro-2-(prop-1-en-1-yl)benzene

Conditions
ConditionsYield
In tetrahydrofuran at 40℃; for 24h; Wittig Olefination; Schlenk technique; Inert atmosphere; Overall yield = 88 percent; Overall yield = 27 mg;A n/a
B n/a
pyridine-2-carbaldehyde
1121-60-4

pyridine-2-carbaldehyde

ethyltriphenylphosphonium acetate
35835-94-0

ethyltriphenylphosphonium acetate

A

Z-1-(2-pyridinyl)-1-propene
54238-00-5

Z-1-(2-pyridinyl)-1-propene

B

(E)-2-(prop-1-en-1-yl)pyridine
52248-74-5

(E)-2-(prop-1-en-1-yl)pyridine

Conditions
ConditionsYield
In tetrahydrofuran at 50℃; for 24h; Wittig Olefination; Schlenk technique; Inert atmosphere; Overall yield = 72 percent; Overall yield = 17 mg;

35835-94-0Downstream Products

35835-94-0Relevant articles and documents

Wittig Olefination Using Phosphonium Ion-Pair Reagents Incorporating an Endogenous Base

Vetter, Anna C.,Gilheany, Declan G.,Nikitin, Kirill

supporting information, p. 1457 - 1462 (2021/03/08)

Despite common perception, the use of strong bases in Wittig chemistry is utterly unnecessary: we report a series of novel ion-pair phosphonium carboxylate reagents which are essentially "storable ylides". These reagents are straightforwardly prepared in excellent yields, and their fluxional nature permits clean olefination of a broad range of aldehydes and even hemiacetals.

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