35896-50-5

Basic information

• Product Name: p-Chlorphenyl-iodmethylsulfon
• Synonyms: p-Chlorphenyl-iodmethylsulfon
• CAS NO: 35896-50-5
• Molecular Weight: 316.547
• Mol File: 35896-50-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: p-Chlorphenyl-iodmethylsulfon(CAS DataBase Reference)
• NIST Chemistry Reference: p-Chlorphenyl-iodmethylsulfon(35896-50-5)
• EPA Substance Registry System: p-Chlorphenyl-iodmethylsulfon(35896-50-5)

Safety Data

• Hazardous Substances Data: 35896-50-5(Hazardous Substances Data)

Upstream product

• 75-11-6 diiodomethane 
• 98-60-2 4-chlorobenzenesulfonyl chloride 
• 14752-66-0 sodium p-chlorobenzenesulphinate 

Downstream Products

• 1414888-18-8 4-chlorophenyl dichloroiodomethyl sulfone 

Relevant articles and documents

The Photochemical Activity of a Halogen-Bonded Complex Enables the Microfluidic Light-Driven Alkylation of Phenols

A mild light-driven protocol for the direct alkylation of phenols is reported. The process is driven by the photochemical activity of a halogen-bonded complex formed upon complexation of the in situ generated electron-rich phenolate anion with the α-iodosulfone. The reaction proceeds rapidly (10 min) under microfluidic conditions, delivering a wide variety of ortho-alkylated products (27 examples, up to 97% yield, >20:1 regioselectivity, on a gram scale), including densely functionalized bioactive phenol derivatives.