359641-96-6

Basic information

• Product Name: (2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)pent-2-ene)ZnCl
• Synonyms: (2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)pent-2-ene)ZnCl
• CAS NO: 359641-96-6
• Molecular Weight: 518.501
• Mol File: 359641-96-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)pent-2-ene)ZnCl(CAS DataBase Reference)
• NIST Chemistry Reference: (2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)pent-2-ene)ZnCl(359641-96-6)
• EPA Substance Registry System: (2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)pent-2-ene)ZnCl(359641-96-6)

Safety Data

• Hazardous Substances Data: 359641-96-6(Hazardous Substances Data)

Upstream product

• 7646-85-7 zinc(II) chloride 
• 205993-24-4 potassium N,N′-bis(2,6-diisopropylphenyl)pentane-2,4-diiminate 

Downstream Products

• 359641-98-8 (2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)pent-2-ene)ZntBu 
• 359641-99-9 (2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)pent-2-ene)ZnPh 
• 473402-46-9 CH(CH₃CNC₆H₃(CH(CH₃)2)2)2ZnH₂BH₂ 
• 473402-44-7 CH(CH₃CNC₆H₃(CH(CH₃)2)2)2ZnCCC₆H₅ 
• 359641-97-7 (2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)pent-2-ene)ZnMe 
• 1449484-30-3 [(2,6-iPr₂-C₆H₃)NC(Me)]2CHZn(p-tBuPy)2(Al(OC(CF₃)3)4) 
• 359642-00-5 (2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)pent-2-ene)ZntBu*THF 
• 1174669-67-0 ({2,6-iPr²H₃C₆N(CH₃)C}₂CH)ZnH 

Relevant articles and documents

Synthesis of a “Masked” Terminal Zinc Sulfide and Its Reactivity with Br?nsted and Lewis Acids

The “masked” terminal Zn sulfide, [K(2.2.2-cryptand)][MeLZn(S)] (2) (MeL={(2,6-iPr2C6H3)NC(Me)}2CH), was isolated via reaction of [MeLZnSCPh3] (1) with 2.3 equivalents of KC8 in THF, in the presence of 2.2.2-cryptand, at ?78 °C. Complex 2 reacts readily with PhCCH and N2O to form [K(2.2.2-cryptand)][MeLZn(SH)(CCPh)] (4) and [K(2.2.2-cryptand)][MeLZn(SNNO)] (5), respectively, displaying both Br?nsted and Lewis basicity. In addition, the electronic structure of 2 was examined computationally and compared with the previously reported Ni congener, [K(2.2.2-cryptand)][tBuLNi(S)] (tBuL={(2,6-iPr2C6H3)NC(tBu)}2CH).

Synthesis and structural characterization of monomeric three-coordinated β-diketoiminate organozinc derivatives

The monomeric zinc compounds with three-coordinated zinc (dipp)NacNacZnCl (1), (dipp)NacNacZnMe (2), (dipp)NacNacZntBu (3), and (dipp)NacNacZnPh (4) were prepared under mild conditions in strong coordinating donor solvents. Compounds 2-4 have been structu