35976-82-0Relevant articles and documents
ALKALINE HYDROLYSIS OF δ-SUBSTITUTED β,γ-UNSATURATED THIOLOPHOSPHATES
Pogosyan, A. S.,Torgomyan A. M.,Indzhikyan, M. G.
, p. 1383 - 1387 (2007/10/02)
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Selective Condensation of titanium Reagent with Carbonyl Compounds
Furuta, Kyoji,Ikeda, Yoshihiko,Meguriya, Noriyuki,Ikeda, Nobuo,Yamamoto, Hisashi
, p. 2781 - 2790 (2007/10/02)
titanium reagent generated easily from allyl ethyl sulfides condensed with aldehydes to give erythro-β-hydroxy sulfides in highly regio- and stereoselective manner.In contrast, crotyl ethyl sulfide reacted with aldehydes affording δ-hydroxy vinyl sulfide exclusively.The substitution pattern of the starting sulfide can have a pronounced effect on the selectivity in this condensation reaction, erythro-β-Hydroxy sulfide obtained was transfromed stereoselectively to the trans-vinyloxirane or 1,3-alkadiene.