359803-53-5 Usage
Reactions
A new, air and moisture-stable, palladium catalyst useful in a broad scope of C-C and C-N coupling reactions. The highlyactive catalyst can tolerate substrates containing a wide variety of functional groups such as alkyls, alkoxides, ketones, aldehydes, esters, amines, trifluoromethyl and nitro groups.
Chemical Properties
Light grey powder
Check Digit Verification of cas no
The CAS Registry Mumber 359803-53-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,5,9,8,0 and 3 respectively; the second part has 2 digits, 5 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 359803-53:
(8*3)+(7*5)+(6*9)+(5*8)+(4*0)+(3*3)+(2*5)+(1*3)=175
175 % 10 = 5
So 359803-53-5 is a valid CAS Registry Number.
359803-53-5Relevant articles and documents
A new generation of air stable, highly active Pd complexes for C-C and C-N coupling reactions with aryl chlorides
Schnyder, Anita,Indolese, Adriano F.,Studer, Martin,Blaser, Hans-Ulrich
, p. 3668 - 3671 (2007/10/03)
High yields in important Pd-catalyzed reactions of aryl chlorides (see scheme) are obtained with complexes consisting of a palladacycle and a secondary phosphane which could be prepared in situ or isolated. The latter were shown to be stable, and easy to handle in air, and the in situ catalysts allow optimization of the catalyst by variation of the two components.
