359844-50-1 Usage
Structure
2,5-Cyclohexadiene-1,4-dione derivative The base structure is a 2,5-cyclohexadiene-1,4-dione with modifications.
Additional groups
Two methoxy groups and one hydroxyethyl group The derivative consists of two methoxy (-OCH3) groups and a hydroxyethyl (-CH2CH2OH) group attached to the base structure.
Usage
Scientific research and pharmaceutical development The compound is often utilized in the fields of organic chemistry and synthesis of novel therapeutic agents.
Applications
Vary depending on the context The specific properties and potential applications of the compound may differ based on the particular situation or experiment it is used in.
Check Digit Verification of cas no
The CAS Registry Mumber 359844-50-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,5,9,8,4 and 4 respectively; the second part has 2 digits, 5 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 359844-50:
(8*3)+(7*5)+(6*9)+(5*8)+(4*4)+(3*4)+(2*5)+(1*0)=191
191 % 10 = 1
So 359844-50-1 is a valid CAS Registry Number.
359844-50-1Relevant articles and documents
A biomimetic approach to dihydrobenzofuran synthesis
Benbow,Katoch-Rouse
, p. 4965 - 4972 (2007/10/03)
A method for an acid-catalyzed construction of dihydrobenzofuran heterocycles (14) from 2-(2′-hydroxyethyl)quinone precursors 10 is presented. The putative oxonium ion intermediate 17 formed by an intramolecular hydroxyl cyclization followed by dehydration is reduced in situ by an added dihydroquinone source. Good to excellent yields of cyclized products are realized in all cases except for highly electron deficient systems, and these suffer reduction prior to oxonium ion formation. All products are monomeric and derived from a two-electron transfer except for 10g, which affords the dimeric dihydrobenzofuran. The amount of cyclization or reduction product is governed by the HOMO/LUMO gap between the quinone substrate and the dihydroquinone additive, and the product distribution can be adjusted by modifying the electronic properties of the added reducing agent.
