359857-37-7

Basic information

• Product Name: N-(4-Iodophenyl)-N'-(2,5-di-tert-butylphenyl)-3,4,9,10-perylenebis(dicarboximide)
• Synonyms: N-(4-Iodophenyl)-N'-(2,5-di-tert-butylphenyl)-3,4,9,10-perylenebis(dicarboximide)
• CAS NO: 359857-37-7
• Molecular Weight: 780.662
• Mol File: 359857-37-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(4-Iodophenyl)-N'-(2,5-di-tert-butylphenyl)-3,4,9,10-perylenebis(dicarboximide)(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-Iodophenyl)-N'-(2,5-di-tert-butylphenyl)-3,4,9,10-perylenebis(dicarboximide)(359857-37-7)
• EPA Substance Registry System: N-(4-Iodophenyl)-N'-(2,5-di-tert-butylphenyl)-3,4,9,10-perylenebis(dicarboximide)(359857-37-7)

Safety Data

• Hazardous Substances Data: 359857-37-7(Hazardous Substances Data)

Upstream product

• 21860-03-7 2,5-di-tert-butylaniline 
• 128-69-8 perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride 
• 540-37-4 p-aminoiodobenzene 
• 83054-80-2 N,N'-bis(2,5-di-tert-butylphenyl)perylene-3,4:9,10-bis(dicarboximide) 
• 118560-99-9 N¹-(2,5-Di-tert-butylphenyl)-3,4,9,10-perylentetracarbonsaeure-3,4-anhydrid-9,10-imid 

Downstream Products

• 525594-18-7 N-(4-[2-[4-[17,18-dihydro-18,18-dimethyl-5-(4-methylphenyl)-17-oxoporphinatozinc(II)-10-yl]phenyl]ethnyl]phenyl)-N'(2,5-di-tert-butylphenyl)-3,4,9,10-perylene-bis(dicarboximide) 
• 359862-69-4 perylenediimide-diphenylethyne-zinc porphyrin dyad 

Relevant articles and documents

Synthesis and excited-state photodynamics of perylene-porphyrin dyads. 1: Parallel energy and charge transfer via a diphenylethyne linker

The photophysical properties of a perylene-porphyrin dyad have been examined with the aim of using this construct for molecular photonics applications. The dyad consists of a perylene-bis(imide) dye (PDI) connected to a zinc porphyrin (Zn) via a diphenylethyne linker (pep). In both polar and nonpolar solvents, the photoexcited perylene unit (PDI*) decays very rapidly (lifetimes of 2.5 (toluene) and 2.4 ps (acetonitrile)) by energy transfer to the porphyrin, forming PDI-pep-Zn* in high yield (80%, toluene; 70% acetonitrile), and hole transfer to the porphyrin, forming PDI--pep-Zn+ in lesser yield (20%, toluene; 30% acetonitrile). In both toluene and acetonitrile, the Zn* excited state subsequently decays with a lifetime of 0.4 ns primarily (80%) by electron transfer to the perylene (forming PDI--pep-Zn+). In the nonpolar solvent (toluene), the PDI--pep-Zn+ charge-transfer product has a lifetime of > 10 ns and decays by charge recombination primarily to the ground state but also by thermal repopulation of the Zn* excited state. The occurrence of the latter process provides a direct experimental measure of the energy of the charge-separated state. In the polar solvent (acetonitrile), the PDI--pep-Zn+ charge-separated state decays much more rapidly (--pep-Zn+) that can be long- or short-lived depending on solvent polarity, indicates the versatility of the perylene-porphyrin motif for a variety of applications in molecular photonics.