359862-14-9

Basic information

• Product Name: (R)-(-)-4-benzyl-3-hexanoyloxazolidin-2-one
• Synonyms: (R)-(-)-4-benzyl-3-hexanoyloxazolidin-2-one
• CAS NO: 359862-14-9
• Molecular Weight: 275.348
• Mol File: 359862-14-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (R)-(-)-4-benzyl-3-hexanoyloxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-(-)-4-benzyl-3-hexanoyloxazolidin-2-one(359862-14-9)
• EPA Substance Registry System: (R)-(-)-4-benzyl-3-hexanoyloxazolidin-2-one(359862-14-9)

Safety Data

• Hazardous Substances Data: 359862-14-9(Hazardous Substances Data)

Upstream product

• 40217-17-2 (R)-4-(phenylmethyl)-2-oxazolidinone 
• 142-61-0 Hexanoyl chloride 
• 142-62-1 hexanoic acid 
• 90719-32-7 (S)-4-Benzyl-2-oxazolidinone 
• 111-64-8 n-octanoic acid chloride 

Downstream Products

• 1336884-41-3 (+)-methyl 6-((1R,2S)-2-((R)-4-benzyl-2-oxooxazolidine-3-carbonyl)-1-hydroxyhexyl)phenazine-1-carboxylate 
• 18908-66-2 3-(bromomethyl)heptane 
• 1134019-90-1 {1-benzyl-4-[(S)-1-((R)-4-benzyl-2-oxo-oxazolidine-3-carbonyl)-pentyl]-piperidin-4-yl}-cyano-acetic acid ethyl ester 
• 1058162-16-5 C₂₇H₃₅NO₆ 
• 1058161-91-3 (R)-4-benzyl-3-((R)-2-((R)-1-hydroxy-2-(4-methoxybenzyloxy)ethyl)hexanoyl)oxazolidin-2-one 
• 4536-23-6 2-methylhexanoic acid 
• 359862-15-0 (2R',4R)-3-(2-methylhexanoyl)-4-benzyl-2-oxazolidinone 

Relevant articles and documents

The Influence of Solubilizing Chain Stereochemistry on Small Molecule Photovoltaics

Three stereochemically pure isomers and two isomeric mixtures of a solution-processable diketopyrrolopyrrole-containing oligothiophene (SMDPPEH) have been used to study the effect of 2-ethylhexyl solubilizing group stereochemistry on the film morphology and bulk heterojunction (BHJ) solar cell characteristics of small molecule organic photovoltaics. The different SMDPPEH stereoisomer compositions exhibit nearly identical optoelectronic properties in the molecularly dissolved state, as well as in amorphous films blended with PCBM. However, for films in which SMDPPEH crystallization is induced by thermal annealing, significant differences in molecular packing between the different stereoisomer formulations are observed. These differences are borne out in photovoltaic device characteristics for which unannealed devices show very similar behavior, while after annealing the RR- and SS-SMDPPEH enantiomers show blue-shifted peak EQE relative to the SMDPPEH isomer mixtures. Unannealed devices made from the most crystalline stereoisomer, meso RS-SMDPPEH, are not completely amorphous, and show improved photocurrent generation as a result. Unlike the other compounds, after thermal annealing the RS-SMDPPEH devices show reduced device performance. The results reveal that the chirality of commonly used 2-ethylhexyl solubilizing chains can have a significant effect on the morphology, absorption, and optimum processing conditions of small molecule organic thin films used as photovoltaic device active layers.

Synthesis of novel analogues of antimycin A3

Four novel analogues of antimycin A3, 1a-d, were synthesized in good overall yields.