359865-08-0

Basic information

• Product Name: 3-p-methoxyphenyl-2α-N-9-phenylfluoren-9-ylamino-1-propanal
• Synonyms: 3-p-methoxyphenyl-2α-N-9-phenylfluoren-9-ylamino-1-propanal
• CAS NO: 359865-08-0
• Molecular Weight: 419.523
• Mol File: 359865-08-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-p-methoxyphenyl-2α-N-9-phenylfluoren-9-ylamino-1-propanal(CAS DataBase Reference)
• NIST Chemistry Reference: 3-p-methoxyphenyl-2α-N-9-phenylfluoren-9-ylamino-1-propanal(359865-08-0)
• EPA Substance Registry System: 3-p-methoxyphenyl-2α-N-9-phenylfluoren-9-ylamino-1-propanal(359865-08-0)

Safety Data

• Hazardous Substances Data: 359865-08-0(Hazardous Substances Data)

Upstream product

• 359865-05-7 3-(4-hydroxy-phenyl)-2-(9-phenyl-9H-fluoren-9-ylamino)-propionic acid methyl ester 
• 359865-06-8 3-(4-methoxy-phenyl)-2-(9-phenyl-9H-fluoren-9-ylamino)-propionic acid methyl ester 
• 3410-66-0 D-tyrosine methyl ester 
• 556-02-5 tyrosine 

Downstream Products

• 359865-12-6 N-9-phenylfluoren-9-ylamino-3α-acetoxy-4α-iodo-2α-(p-methoxybenzyl)pyrrolidine 
• 359865-11-5 4α-N-9-phenylfluoren-9-ylamino-3α-acetoxy-5-p-methoxyphenyl-1-pentene 
• 359865-10-4 4α-N-9-phenylfluoren-9-ylamino-3α-hydroxy-5-p-methoxyphenyl-1-pentene 
• 604789-37-9 (2R,3S,4R)-deacetylanisomycin 
• 853092-28-1 (2R,3R,4R)-anisomycin 
• 853092-30-5 (2R,3R,4R)-2-(4-methoxybenzyl)pyrrolidine-3,4-diol 
• 853092-44-1 (2R,3R,4R)-N-(9-phenylfluoren-9-yl)-4-O-benzoylanisomycin 
• 853092-42-9 (2R,3R,4R)-N-(9-phenylfluoren-9-yl)-3-acetoxy-4-iodo-2-(p-methoxybenzyl)pyrrolidine 
• 853092-50-9 (2R,3R,4R)-N-(9-phenylfluoren-9-yl)anisomycin 
• 853092-46-3 (2R,3R,4R)-N-(9-phenylfluoren-9-yl)deacetylanisomycin 
• 853092-48-5 (2R,3R,4S)-N-(9-phenylfluoren-9-yl)deacetylanisomycin 
• 853092-54-3 (2R,3S,4R)-N-(9-phenylfluoren-9-yl)deacetylanisomycin 
• 853092-40-7 (3S,4R)-4-(N-9-phenylfluoren-9-yl)amino-3-acetoxy-5-(p-methoxyphenyl)-1-pentene 
• 853092-36-1 (3S,4R)-4-(N-9-phenylfluoren-9-yl)amino-3-hydroxy-5-(p-methoxyphenyl)-1-pentene 

Relevant articles and documents

Diastereoselective iodoamidation of 3-acetoxybut-1-Enylamines: Synthesis of 3-acetoxy-4-iodo-2-(p-methoxybenzyl)pyrrolidines

3α-Acetoxy-4α-iodo-2α-(p-methoxybenzyl)pyrrolidine (2) and its enanti-omer (3) were synthesized via diastereoselective iodoamidation, starting from D- or L-tyrosine. The key step contains unfavorable 5-endo-trig cyclization and the diastereoselective addition of ethynylmagnesium bromide to aldehydes (9) by the chelation-controlled Cram cyclic model.