361344-97-0

Basic information

• Product Name: tetrakis(4-thiylphenyl)methane
• Synonyms: tetrakis(4-thiylphenyl)methane
• CAS NO: 361344-97-0
• Molecular Weight: 448.698
• Mol File: 361344-97-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tetrakis(4-thiylphenyl)methane(CAS DataBase Reference)
• NIST Chemistry Reference: tetrakis(4-thiylphenyl)methane(361344-97-0)
• EPA Substance Registry System: tetrakis(4-thiylphenyl)methane(361344-97-0)

Safety Data

• Hazardous Substances Data: 361344-97-0(Hazardous Substances Data)

Upstream product

• 105309-59-9 tetrakis(4-bromophenyl)methane 

Relevant articles and documents

Tetrakis-(4-thiyphenyl)methane: Origin of a reversible 3D-homopolymer

The efficient syntheses of tetrakis(thiophenol)methane and of a new poly(disulfide) hyper-crosslinked polymer based on the former monomer are described. Controlled de-polymerization as well as surface post- functionalization are successfully conducted on this novel material. Direct prove of post-functionalization is obtained through solid-state fluorescence emission spectroscopy, and the number of unreacted thiol-functions on the surface of the polymeric material is indirectly quantified by de-polymerization of the post-functionalized material. The efficient generation of a hyper-crosslinked poly(disulfide) is described. After high yielding synthesis of the monomer tetrakis-(4-thiylphenyl)methane, the polymeric material is obtained in excellent yield under mild reaction conditions. Combination of controlled de-polymerization under bio-compatible conditions and postfunctionalization gives access to the number of free termini at the surface.