36153-04-5

Basic information

• Product Name: (1,4-diphenylbutane)tricarbonylchromium
• Synonyms: (1,4-diphenylbutane)tricarbonylchromium
• CAS NO: 36153-04-5
• Molecular Weight: 346.346
• Mol File: 36153-04-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1,4-diphenylbutane)tricarbonylchromium(CAS DataBase Reference)
• NIST Chemistry Reference: (1,4-diphenylbutane)tricarbonylchromium(36153-04-5)
• EPA Substance Registry System: (1,4-diphenylbutane)tricarbonylchromium(36153-04-5)

Safety Data

• Hazardous Substances Data: 36153-04-5(Hazardous Substances Data)

Upstream product

• 108319-37-5 (1,4-diphenylbutane)bis(tricarbonylchromium) 
• 1076-43-3 benzene-d6 
• 1083-56-3 1,4-diphenylbutane 
• 199620-14-9 chromium⁽⁰⁾ hexacarbonyl 

Downstream Products

• 113031-49-5 (1-(4''-acetylphenyl)-4-phenylbutane)tricarbonylchromium 
• 108295-91-6 (1,1-dideuterio-1,4-diphenylbutane)tricarbonylchromium 

Relevant articles and documents

Neighboring group participation in organometallic chemistry: Anchimeric assistance in catalyzed arene exchange reactions of (diarylalkane)tricarbonylchromium complexes

Nucleophilic catalysis of the migration of a tricarbonylchromium group from one ring to the other in diarylalkane tricarbonyl derivatives has been observed and compared with catalysis of external exchange. Internal catalysis by a neighboring tricarbonylchromium is also being reported. These results demonstrate the intermediacy of a chromium complex having three carbonyl groups, ketone, and two η2-bound arenes. The consequences of this result for metal exchange reactions are discussed.

Neighboring Group Participation in Organometallic Chemistry: Internal Exchange in (Diarylalkane)tricarbonylchromium Complexes

The rates of internal and external exchange of (diarylalkane)tricarbonylchromium complexes in benzene/cyclohexane mixtures have been determined.Neighbouring group participation is demonstrated in all complexes and follows an order with respect to ring siz