3618-76-6Relevant articles and documents
Reactions of hydroxyl-containing compounds with tert-butyl hydroperoxide in the presence of chromium tetra-tert-butoxide
Stepovik,Zaburdaeva,Fukin,Karaghiosoff
, p. 2547 - 2559 (2015/12/30)
Primary and secondary aliphatic, alkylaromatic, cyclic, and organoelement alcohols are efficiently oxidized by tert-butyl hydroperoxide in the presence of both equimolar and catalytic quantities of chromium tetra-tert-butoxide (C6H6, 20°C). α-Diols containing tertiary hydroxyl groups interact with this system via oxidative splitting of the carbon scaffold. The oxidation includes the stages of formation and decomposition of chromium-containing peroxy compounds. Further transformations of the carbonyl compounds depend on the structure of radicals in the molecules.
Synthesis of vincamine
Rossey,Wick,Wenkert
, p. 4745 - 4749 (2007/10/02)
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