36195-56-9

Basic information

• Product Name: [(2E)-but-2-en-1-ylsulfanyl]benzene
• Synonyms: trans-1-(Phenylthio)-2-butene
• CAS NO: 36195-56-9
• Molecular Formula: C₁₀H₁₂S
• Molecular Weight: 164.2673
• Mol File: 36195-56-9.mol
• Article Data: 24

Chemical Properties

• Boiling Point: 231.5°C at 760 mmHg
• Flash Point: 92.4°C
• Density: 1g/cm³
• Vapor Pressure: 0.0941mmHg at 25°C
• Refractive Index: 1.565
• CAS DataBase Reference: [(2E)-but-2-en-1-ylsulfanyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: [(2E)-but-2-en-1-ylsulfanyl]benzene(36195-56-9)
• EPA Substance Registry System: [(2E)-but-2-en-1-ylsulfanyl]benzene(36195-56-9)

Safety Data

• Hazardous Substances Data: 36195-56-9(Hazardous Substances Data)

Upstream product

• 4784-77-4 (E)-1-Bromo-2-butene 
• 108-98-5 thiophenol 
• 21106-26-3 trans-1-Phenylmercaptobuten-⁽¹⁾ 
• 4285-49-8 homoallyl phenyl sulfide 
• 504-61-0 (E)-but-2-enol 
• 598-32-3 2-hydroxy-3-butene 
• 591-97-9 1-chloro-2-butene 
• 563-52-0 2-chloro-3-butene 
• 4894-61-5 trans-but-2-enyl chloride 
• 103185-13-3 (E)-crotyl methyl carbonate 
• 4784-77-4 (E/Z)-crotyl bromide 
• 591-51-5 phenyllithium 
• 930-69-8 sodium thiophenolate 
• 6117-91-5 (E/Z)-2-buten-1-ol 

Downstream Products

• 78905-12-1 phenyl 1-trimethylsilylcrotyl sulfide 
• 134427-72-8 ethyl 3-methyl-2-(phenylthio)-2-(trifluoromethyl)-4-pentenoate 
• 35802-48-3 (1-methyl-2-propenyl)dimethylphenylsilane 
• 106070-43-3 ((E)-But-2-enyl)-dimethyl-phenyl-silane 
• 138223-98-0 bis(methoxymethyl) ether of 2,3-dihydro-5,7-dihydroxy-2-<1-(2-phenylthio-3-pentenyl)>benzofuran 
• 138224-02-9 5,7-Bis-(1-ethoxy-ethoxy)-2-((E)-2-phenylsulfanyl-pent-3-enyl)-2,3-dihydro-benzofuran 
• 21106-26-3 trans-1-Phenylmercaptobuten-⁽¹⁾ 
• 72863-24-2 (E)-(but-2-en-1-ylsulfonyl)benzene 
• 86838-05-3 γ-methylallyl phenyl sulphoxide 
• 36195-55-8 (Z)-but-2-en-1-yl phenyl sulfide 
• 25201-44-9 2-methyl-1-phenyl-3-butene-1-ol 
• 75851-76-2 (Z)-1-phenyl-3-penten-1-ol 
• 13733-59-0 (E/Z)-methyl-3-(phenylthio) acrylate 
• 3708-35-8 Ethyl 2-(ethoxycarbonyl)-5-phenyl-4-pentenoate 

Relevant articles and documents

Direct oxidative allylic and vinylic amination of alkenes through selenium catalysis

Bringing "N" into the game: The direct chemoselective nitrogenation of unactivated alkenes can be achieved through oxidative selenium catalysis (see scheme). This method provides a broad variety of allylic imides in yields of up to 89 % using N-fluorobenzenesulfonimide (NFSI) as the terminal oxidant and nitrogen source. Furthermore, an unprecedented selenium-catalyzed vinylic C(sp2)-H nitrogenation was discovered. Copyright

Silica nanoparticles as a reusable catalyst: A straightforward route for the synthesis of thioethers, thioesters, vinyl thioethers and thio-Michael adducts under neutral reaction conditions

A simple and straightforward route for the synthesis of thioethers, thioesters, vinyl thioethers and thio-Michael adducts has been demonstrated using silica nanoparticles (NPs) as a reusable catalyst via the 1,2-addition of thiols to alkenes, alkynes and alkyl/acyl halides, and the 1,4-addition of thiols to conjugated alkenes at room temperature.

Selective allylation of arenethiols using water-soluble palladium complex catalyst in recyclable water/hexane biphasic media

Allylation of arenethiols by allylic alcohol with sterically hindered carbon of the allylic moiety is smoothly catalyzed by Pd(OAc)2/TPPTS in biphasic water/hexane media under ambient conditions. The catalyst water layer can be repeatedly reuse