36346-97-1Relevant articles and documents
Synthesis, Solid-State Structures, and Computational Studies of Half-Sandwich Cp?BeX (X = Cl, Br, I) Compounds
Naglav, Dominik,Tobey, Briac,Neumann, Anja,Bl?ser, Dieter,W?lper, Christoph,Schulz, Stephan
, p. 3072 - 3078 (2015)
The solid-state structures of half-sandwich beryllium complexes Cp?BeX (X = Cl (1), Br (2), I (3)) are described. All attempts to synthesize Cp?BeF (4) by reaction of 1-3 with several fluorinating reagents such as AgF2, XeF2, 4-FC6H4IF2, AgF, NaF, and Me4NF failed. However, the reaction of 3 and AgF in resulted in the unexpected synthesis of the known beryllocene Cp?2Be (5). Quantum-chemical calculations were performed to investigate the electronic structures of 1-4. (Chemical Equation Presented).
THE CRYSTAL STRUCTURE OF CYCLOPENTADIENYLBERYLLIUM CHLORIDE
Goddard, Richard,Akhtar, J.,Starowieyski, Kazimierz B.
, p. 149 - 154 (1985)
The crystal structure of CpBeCl has been determined by X-ray diffraction.This shows that the molecule has the same structure in the solid state as in the gas phase.No significant intermolecular interactions were observed although such interactions had bee
