3644-91-5

Basic information

• Product Name: Silane, triethyl(4-methylphenyl)-
• CAS NO: 3644-91-5
• Molecular Formula: C13H22Si
• Molecular Weight: 206.403
• Mol File: 3644-91-5.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: Silane, triethyl(4-methylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, triethyl(4-methylphenyl)-(3644-91-5)
• EPA Substance Registry System: Silane, triethyl(4-methylphenyl)-(3644-91-5)

Safety Data

• Hazardous Substances Data: 3644-91-5(Hazardous Substances Data)

Upstream product

• 617-86-7 triethylsilane 
• 108-88-3 toluene 
• 1777-03-3 2-triethylsilylacetylene 
• 78-79-5 isoprene 
• 106-44-5 p-cresol 
• 745783-97-5 triethyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane 
• 132680-48-9 O-4-methylphenyl N,N-diethylcarbamate 
• 106-43-4 para-chlorotoluene 
• 350-42-5 4-methylbenzoyl fluoride 
• 6140-15-4 trimethyl-p-tolylammonium iodide 
• 99-94-5 p-Toluic acid 
• 874-60-2 4-methyl-benzoyl chloride 
• 1900-85-2 phenyl p-methylbenzoate 
• 106-38-7 para-bromotoluene 

Downstream Products

• 18414-83-0 triethyl(4-ethylphenyl)silane 
• 19061-64-4 (4-bromomethylphenyl)triethylsilane 
• 18410-46-3 triethyl-(4-methyl-3-nitro-phenyl)-silane 

Relevant articles and documents

Continuous-flow Si-H functionalizations of hydrosilanesviasequential organolithium reactions catalyzed by potassiumtert-butoxide

We herein report an atom-economic flow approach to the selective and sequential mono-, di-, and tri-functionalizations of unactivated hydrosilanesviaserial organolithium reactions catalyzed by earth-abundant metal compounds. Based on the screening of various additives, we found that catalytic potassiumtert-butoxide (t-BuOK) facilitates the rapid reaction of organolithiums with hydrosilanes. Using a flow microreactor system, various organolithiums bearing functional groups were efficiently generatedin situunder mild conditions and consecutively reacted with hydrosilanes in the presence oft-BuOK within 1 min. We also successfully conducted the di-funtionalizations of dihydrosilane by sequential organolithium reactions, extending to a gram-scale-synthesis. Finally, the combinatorial functionalizations of trihydrosilane were achieved to give every conceivable combination of tetrasubstituted organosilane libraries based on a precise reaction control using an integrated one-flow system.

Iron-Catalyzed Silylation of (Hetero)aryl Chlorides with Et3SiBpin

To date, the iron-catalyzed construction of C-heteroatom bonds has been less developed due to the difficulty of transmetalation with heteroatom anions and the sluggish reductive elimination. Herein we report an iron-catalyzed method for the silylation of

Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.