36476-32-1

Basic information

• Product Name: Ethyl-α,α'-bis(phenylthio)acetoacetat
• Synonyms: Ethyl-α,α'-bis(phenylthio)acetoacetat
• CAS NO: 36476-32-1
• Molecular Weight: 346.471
• Mol File: 36476-32-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Ethyl-α,α'-bis(phenylthio)acetoacetat(CAS DataBase Reference)
• NIST Chemistry Reference: Ethyl-α,α'-bis(phenylthio)acetoacetat(36476-32-1)
• EPA Substance Registry System: Ethyl-α,α'-bis(phenylthio)acetoacetat(36476-32-1)

Safety Data

• Hazardous Substances Data: 36476-32-1(Hazardous Substances Data)

Upstream product

• 14204-27-4 N-phenylthiophthalimide 
• 141-97-9 ethyl acetoacetate 
• 14204-24-1 N-(phenylthio)succinimide 
• 258822-89-8 3-Phenylsulfenyl-2-(N-cyanoimino)thiazolidine 
• 931-59-9 benzenesulfenyl chloride 

Downstream Products

• 27872-73-7 2-phenylsulfanyl-acetoacetic acid ethyl ester 

Relevant articles and documents

A new sulfenylation reagent, 3-phenylsulfenyl-2-(N- cyanoimino)thiazolidine, and its optically active version

We have developed a new sulfenylation reagent, 3-phenylsulfenyl-2-(N- cyanoimino)thiazolidine 3, that is readily available and stable upon storage. Compound 3 easily reacts with amines or thiols to give the corresponding sulfenamides or asymmetrical disulfides in excellent yields. It was also found that the α-sulfenylation reaction of carbonyl compounds with 3 proceeds smoothly. Furthermore, optically active 4-diphenylmethyl derivative 4 was synthesized as an asymmetric sulfenylation reagent, which realized 96% e.e. upon α-sulfenylation of a cyclic β-keto ester.