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36519-51-4

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36519-51-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 36519-51-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,6,5,1 and 9 respectively; the second part has 2 digits, 5 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 36519-51:
(7*3)+(6*6)+(5*5)+(4*1)+(3*9)+(2*5)+(1*1)=124
124 % 10 = 4
So 36519-51-4 is a valid CAS Registry Number.

36519-51-4Relevant articles and documents

Excited-state hydroxide ion release from a series of acridinol photobases

Xie, Yun,Ilic, Stefan,Skaro, Sanja,Maslak, Veselin,Glusac, Ksenija D.

, p. 448 - 457 (2017/12/08)

The excited-state heterolysis of acridinol-based derivatives leads to the release of the OH-ion and the formation of the corresponding acridinium cations. To evaluate the parameters that control the reaction barriers, the kinetics of excited-state OH-release from a series of acridinol photobases were studied using transient absorption spectroscopy. The rate constants were obtained in three solvents (methanol, butanol, and isobutanol), and the data were modeled using Marcus theory. The intrinsic reorganization energies obtained from these fits were found to correlate well with the solvent reorganization energies calculated using dielectric continuum model, suggesting that the excited-state OH-release occurs along the solvent reaction coordinate. Furthermore, the ability of acridinol photobases to photoinitiate chemical reactions was demonstrated using the Michael reaction between dimethylmalonate and nitrostyrene.

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