365441-82-3

Basic information

• Product Name: Carbamic acid, [(4-methoxyphenyl)[(4-methylphenyl)sulfonyl]methyl]-, 1,1-dimethylethyl ester
• CAS NO: 365441-82-3
• Molecular Formula: C20H25NO5S
• Molecular Weight: 391.488
• Mol File: 365441-82-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Carbamic acid, [(4-methoxyphenyl)[(4-methylphenyl)sulfonyl]methyl]-, 1,1-dimethylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, [(4-methoxyphenyl)[(4-methylphenyl)sulfonyl]methyl]-, 1,1-dimethylethyl ester(365441-82-3)
• EPA Substance Registry System: Carbamic acid, [(4-methoxyphenyl)[(4-methylphenyl)sulfonyl]methyl]-, 1,1-dimethylethyl ester(365441-82-3)

Safety Data

• Hazardous Substances Data: 365441-82-3(Hazardous Substances Data)

Upstream product

• 4248-19-5 tert-butyl carbazate 
• 123-11-5 4-methoxy-benzaldehyde 
• 824-79-3 sodium 4-methylbenzenesulfinate 

Downstream Products

• 1071052-10-2 tert-butyl [2-cyano-1-(4-methoxy-phenyl)-allyl]carbamate 
• 1071051-87-0 methyl 2-[tert-butoxycarbonylamino(4-methoxy-phenyl)methyl]acrylate 
• 1071052-02-2 ethyl 2-[tert-butoxycarbonylamino(4-methoxy-phenyl)methyl]acrylate 
• 926308-21-6 ((1S,2S)-1-(4-methoxyphenyl)-2-methyl-3-oxopropyl)carbamic acid tert-butyl ester 
• 80907-19-3 ethyl 2?(2?(4?methoxyphenyl)?4?oxo?4H?chromen?3?yl)acetate 
• 1448796-45-9 (3S,4S)-N-(2-(4-benzyloxyphenyl)ethyl)-Benzyl-3-isopropyl-4-(4-methoxyphenyl)-2-oxo-4-(propanamido)butanamide 
• 1448796-88-0 (3R,4R)-4-(S-2-((benzyloxycarbonyl)amino)-3-methylbutanamido)-3-isopropyl-4-(4-methoxyphenyl)-N-methyl-2-oxobutanamide 
• 1448796-39-1 (3S,4S)-4-(S-2-((benzyloxycarbonyl)amino)-3-methylbutanamido)-3-isopropyl-4-(4-methoxyphenyl)-N-methyl-2-oxobutanamide 
• 1213263-38-7 tert-butyl (1S,2R)-2-formyl-1-(4-methoxyphenyl)-3-methylbutylcarbamate 
• 1323441-60-6 C₁₄H₂₄NO₄P*ClH 
• 1323441-54-8 diisopropyl [isothiocyanato(4-methoxyphenyl)methyl]phosphonate 

Relevant articles and documents

A novel bis-thiourea organocatalyst for the asymmetric aza-Henry reaction

A novel bis-thiourea/2,2′-diaminobinaphthalene (BINAM)-based catalyst for the asymmetric aza-Henry reaction has been developed. This catalyst promotes the reaction of N-Boc imines with nitroalkanes to afford β-nitroamines with good yields and high enantioselectivities. This catalyst has the advantage that it can be prepared in a single step from commercially available materials. A model is proposed for the catalyst action where both components of the reaction are activated simultaneously by hydrogen bonding. Regardless of the mechanism, the success of the present catalyst demonstrates the potential of bis-thioureas as an interesting class of relatively unexplored catalysts.

Reductive BOC-amination of aldehydes

Base-assisted elimination-reduction of α-amidoalkyl sulfones with sodium borohydride proceeds in tetrahydrofuran at room temperature leading to the corresponding BOC-amines in good yields.