366007-10-5

Basic information

• Product Name: [Zn(2-(phenylazo)pyridine)Cl₂*CH₃OH]
• CAS NO: 366007-10-5
• Molecular Weight: 351.551
• Mol File: 366007-10-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Zn(2-(phenylazo)pyridine)Cl₂*CH₃OH](CAS DataBase Reference)
• NIST Chemistry Reference: [Zn(2-(phenylazo)pyridine)Cl₂*CH₃OH](366007-10-5)
• EPA Substance Registry System: [Zn(2-(phenylazo)pyridine)Cl₂*CH₃OH](366007-10-5)

Safety Data

• Hazardous Substances Data: 366007-10-5(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 2569-57-5 2-(phenylazo)pyridine 

Relevant articles and documents

Synthesis, spectral and electrochemical studies of 2-(arylazo)heterocycle complexes of zinc(II). Single-crystal X-ray structure of [Zn(papm)Cl2·CH3OH] (papm = 2-(phenylazo)pyrimidine)

2-(Arylazo)pyridines (aap) (R-C6H4-N=N-C5H4N, 1) and 2-(arylazo)pyrimidines (aapm) (R-C6H4-N=N-C4H3N2, 2); R = H (a), o-Me (b), m-Me (c), p-Me (d), p-Cl (e) are used to synthesise title compounds. The complexes are characterised by elemental analyses, IR, UV - Vis and 1H NMR spectral data. Single-crystal X-ray structure of dichloro-{2-(phenylazo)pyrimidine}-zinc(II) methanol suggests that the complex is a distorted trigonal bipyramidal symmetric around Zn(II), and Cl(1), Cl(2), N(4) (N (azo)) make the trigonal plane. Zn(II) moves downwards by 0.12 ? from the centre of gravity of the plane. Two axial positions are occupied by N(1) (N(pyrimidine)) and methanol-O. Molecular packing shows one-dimensional infinite chain via hydrogen bonding. The EHMO calculation has been carried out to explain the electronic behaviour of the complexes and the results are compared with that of copper(I) complex.