36616-60-1

Basic information

• Product Name: (1alpha,4alpha,6alpha)-(+)-1-methyl-4-(1-methylvinyl)-7-oxabicyclo[4.1.0]heptan-2-one
• Synonyms: (1alpha,4alpha,6alpha)-(+)-1-methyl-4-(1-methylvinyl)-7-oxabicyclo[4.1.0]heptan-2-one;(+)-Carvone epoxide;1-Carvone oxide;7-Oxabicyclo[4.1.0]heptan-2-one, 1-methyl-4-(1-methylethenyl)-, (1.alpha.,4.alpha.,6.alpha.)-(+)-;Nsc316066;p-Menth-8-en-2-one, 1,6-epoxy-, (1R,4R,6R)-(-)-;(+)-2,3-Epoxy-5-isopropenyl-2-Methylcyclohexanone;(1R,4R,6R)-1-Methyl-4-(1-Methylethenyl)-7-oxabicyclo[4.1.0]heptan-2-one
• CAS NO: 36616-60-1
• Molecular Formula: C₁₀H₁₄O₂
• Molecular Weight: 166.21696
• EINECS: 253-128-6
• Product Categories: Chiral Reagents;Intermediates & Fine Chemicals;Pharmaceuticals;Chiral Reagents, Pharmaceuticals, Intermediates & Fine Chemicals
• Mol File: 36616-60-1.mol
• Article Data: 59

Chemical Properties

• Appearance: /
• Storage Temp.: Refrigerator
• Solubility: Chloroform (Slightly), Methanol (Slightly)
• CAS DataBase Reference: (1alpha,4alpha,6alpha)-(+)-1-methyl-4-(1-methylvinyl)-7-oxabicyclo[4.1.0]heptan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1alpha,4alpha,6alpha)-(+)-1-methyl-4-(1-methylvinyl)-7-oxabicyclo[4.1.0]heptan-2-one(36616-60-1)
• EPA Substance Registry System: (1alpha,4alpha,6alpha)-(+)-1-methyl-4-(1-methylvinyl)-7-oxabicyclo[4.1.0]heptan-2-one(36616-60-1)

Safety Data

• Hazardous Substances Data: 36616-60-1(Hazardous Substances Data)

Usage

Chemical Properties

Clear Liquid

Uses

Different sources of media describe the Uses of 36616-60-1 differently. You can refer to the following data:
1. As a terpenoid, (1alpha,4alpha,6alpha)-(+)-1-methyl-4-(1-methylvinyl)-7-oxabicyclo[4.1.0]heptan-2-one can be used as a reagent in the preparation of flavoring compounds and pharmaceutical drugs.
2. A terpenoid used as a reagent in the preparation of flavoring compounds and pharmaceutical drugs.

Synthesis Reference(s)

Tetrahedron Letters, 29, p. 5815, 1988 DOI: 10.1016/S0040-4039(00)82200-5

Upstream product

• 99-49-0 Carvone 
• 6485-40-1 (R)-Carvone 
• 121078-47-5 (-)-Carvone diepoxide 
• 99-48-9 5-Isopropenyl-2-methyl-cyclohex-2-enol 

Downstream Products

• 2102-58-1 (+)-trans-carveol 
• 1309930-37-7 (5R,6R)-5-tert-butyldimethylsilyloxy-6-methyl-2-cyclohexenone 
• 1309930-42-4 (5R,6R)-5-tert-butyldimethylsilyloxy-2-iodo-6-methyl-2-cyclohexenone 
• 1309930-44-6 (1R,5R,6S)-5-tert-butyldimethylsilyloxy-2-iodo-6-methylcyclohex-2-enol 
• 1309930-46-8 [(1R,5R,6S)-5-benzyloxy-4-iodo-6-methylcyclohex-3-enyloxy]-tert-butyldimethylsilane 
• 485388-83-8 (4E,7S)-N-{(2R)-2-[(4R,5R)-4-hydroxy-5-methyl-6-oxocyclohex-1-enyl]-2-methoxyethyl}-7-methoxydodec-4-enamide 
• 1309930-36-6 N-{(2S)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methyl-1-cyclohexenyl]-2-hydroxyethyl}-isoindoline-1,3-dione 
• 1309930-49-1 2-{[(2R,4S,7R,8S,8aR)-7-(tert-butyldimethylsilyloxy)-8-methyl-2-phenyl-6,7,8,8a-tetrahydro-4H-benzo[d][1,3]dioxin-4-yl]methyl}-isoindoline-1,3-dione 
• 1309930-51-5 (4E,7S)-N-{(2S)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide 
• 1309930-52-6 2-{(2S)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methyl-1-cyclohexenyl]-2-methoxyethyl}-isoindoline-1,3-dione 
• 1309930-54-8 (4E,7S)-N-{(2S)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methyl-cyclohex-1-enyl]-2-methoxyethyl}-7-methoxydodec-4-enamide 
• 1309930-55-9 (4E,7S)-N-{(2S)-2-[(4R,5R)-4-(tert-butyldimethylsilyloxy)-5-methyl-6-oxocyclohex-1-enyl]-2-methoxyethyl}-7-methoxydodec-4-enamide 
• 1309930-56-0 (4E,7S)-N-{2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-oxoethyl}-7-methoxydodec-4-enamide 
• 1309930-59-3 (4E,7S)-N-{(2R)-2-[(4R,5S,6R)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-methylcyclohex-1-enyl]-2-hydroxyethyl}-7-methoxydodec-4-enamide 

Relevant articles and documents

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Activation of H2O2over Zr(IV). Insights from Model Studies on Zr-Monosubstituted Lindqvist Tungstates

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