36638-43-4

Basic information

• Product Name: (2,4-dinitrophenyl)hydrazone of methoxyacetaldehyde
• CAS NO: 36638-43-4
• Molecular Weight: 254.202
• Mol File: 36638-43-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2,4-dinitrophenyl)hydrazone of methoxyacetaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: (2,4-dinitrophenyl)hydrazone of methoxyacetaldehyde(36638-43-4)
• EPA Substance Registry System: (2,4-dinitrophenyl)hydrazone of methoxyacetaldehyde(36638-43-4)

Safety Data

• Hazardous Substances Data: 36638-43-4(Hazardous Substances Data)

Upstream product

• 10312-83-1 methoxyacetaldehyde 
• 119-26-6 (2,4-dinitro-phenyl)-hydrazine 

Relevant articles and documents

Kinetics and mechanism of the oxidation of aliphatic primary alcohols by imidazolium fluorochromate

The oxidation of nine aliphatic primary alcohols by imidazolium fluorochromate (IFC) in dimethylsulphoxide leads to the formation of corresponding aldehydes. The reaction is first order with respect to IFC. A Michaelis-Menten type kinetics is observed with respect to alcohols. The reaction is promoted by hydrogen ions; the hydrogen-ion dependence has the form : kobs = a + b [H+]. The oxidation of [1,1- 2H2]ethanol (MeCD2OH) exhibits a substantial primary kinetic isotope effect (kH/kD = 5.87 at 298 K). The reaction has been studied in nineteen different organic solvents. The solvent effect was analysed using Taft's and Swain's multiparametric equations. The rate of oxidation is susceptible to both polar and steric effects of the substituents. A suitable mechanism has been proposed.

Oxidation of aliphatic primary alcohols by morpholinium chlorochromate: A kinetic and mechanistic approach

The oxidation of nine aliphatic primary alcohols by morpholinium chlorochromate (MCC) in dimethylsulfoxide leads to the transformation of alcohols to the corresponding aldehydes. The reaction is first order with respect to both MCC and the alcohol both. The reaction is catalysed by hydrogen ions. The hydrogen-ion dependence has the form: kobs = a + A[H +]. The oxidation of [1,1-2H2]ethanol (MeCD2OH) exhibits a substantial primary kinetic isotope effect. The reaction has been studied in nineteen different organic solvents. The solvent effect was analysed using Taft's and Swain's multiparametric equations. The rate of oxidation is susceptible to both polar and steric effects of the substituents. A suitable mechanism has been proposed.