36914-79-1

Basic information

• Product Name: 2,4-DibroMophenol Acetate
• Synonyms: 2,4-DibroMophenol Acetate
• CAS NO: 36914-79-1
• Molecular Formula: C₈H₆Br₂O₂
• Molecular Weight: 294
• Product Categories: Aromatics;Miscellaneous Reagents;Aromatics, Miscellaneous Reagents
• Mol File: 36914-79-1.mol
• Article Data: 5

Chemical Properties

• Melting Point: 33.1-33.4 °C
• Boiling Point: 303.7°C at 760 mmHg
• Flash Point: 137.5°C
• Appearance: /
• Density: 1.843g/cm³
• Vapor Pressure: 0.000914mmHg at 25°C
• Refractive Index: 1.578
• Storage Temp.: -20°C Freezer
• Solubility: Chloroform (Slightly), Methanol (Slightly)
• CAS DataBase Reference: 2,4-DibroMophenol Acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-DibroMophenol Acetate(36914-79-1)
• EPA Substance Registry System: 2,4-DibroMophenol Acetate(36914-79-1)

Safety Data

• Hazardous Substances Data: 36914-79-1(Hazardous Substances Data)

Usage

Uses

2,4-Dibromophenol Acetate (cas# 36914-79-1) is a compound useful in organic synthesis.

InChI:InChI=1/C8H6Br2O2/c1-5(11)12-8-3-2-6(9)4-7(8)10/h2-4H,1H3

Upstream product

• 615-58-7 2,4-dibromophenol 
• 75-36-5 acetyl chloride 
• 607-95-4 2,4,6-tribromophenyl acetate 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 108-36-1 1,3-dibromobenzene 
• 108-24-7 acetic anhydride 

Downstream Products

• 94353-39-6 2,4-dicyanophenyl acetate 
• 34133-58-9 4-hydroxy-isophthalonitrile 
• 1927-95-3 4-bromophenyl acetate 
• 24539-95-5 2,4-dibromo-6-ethylphenol 
• 81877-99-8 2-(3'-pyridiloxy)acetophenone 
• 81878-06-0 1-(3,5-Dibromo-2-hydroxy-phenyl)-3-pyridin-3-yl-propane-1,3-dione 
• 81877-80-7 (E)-1-(3,5-Dibromo-2-hydroxy-phenyl)-3-pyridin-3-yl-propenone 
• 22362-66-9 3,5-dibromo-2-hydroxyacetophenone 

Relevant articles and documents

Ligand-Promoted Palladium-Catalyzed C?H Acetoxylation of Simple Arenes

The palladium-catalyzed C?H oxidation of simple arenes is an attractive strategy to obtain phenols, which have many applications in the fine chemicals industry. Although some advances have been made in this research area, low reactivity and selectivity are, in general, observed. This report describes a new catalytic system for the efficient C?H acetoxylation of simple arenes based on Pd(OAc)2 and a pyridinecarboxylic acid ligand.

Polymer-supported gadolinium triflate as a convenient and efficient Lewis acid catalyst for acetylation of alcohols and phenols

A polymer-supported gadolinium triflate (CMPS-IM-Gd) catalyst was prepared from chloromethyl polystyrene (CMPS) resin using a simple and convenient procedure. This polymeric catalyst was used as an efficient Lewis acid catalyst for the acetylation of various alcohols and phenols with acetic anhydride, affording high yields under mild conditions. The reaction was completed in a short period of time with small amounts of the catalyst. The catalyst was reused over 10 times without any significant loss of its catalytic activity.

The Synthesis and Transition Temperatures of Ester Derivatives of 2-Fluoro-4-hydroxy- and 3-Fluoro-4-hydroxybenzonitriles also Incorporating Aliphatic Ring Systems

The synthesis and liquid-crystal transition temperatures of forty ester derivatives of 2-fluoro-4-hydroxybenzonitrile and 3-fluoro-4-hydroxybenzonitrile are reported.The esters contain the trans-1,4-disubstituted cyclohexane or the 1,4-disubstituted bicyclooctane rings (some contain an additional phenyl ring).Many of the novel F-substituted esters exhibit substantially higher nematic-isotropic transition temperatures than the corresponding unsubstituted esters.The order of clearing points of these laterally substituted esters differing only in the presence of a benzene ring and the above-mentioned rings is established.