369354-91-6

Basic information

• Product Name: toluene-4-sulfonic acid 3,3-dimethyl-1-(toluene-4-sulfonyl)-aziridin-2-ylmethyl ester
• Synonyms: toluene-4-sulfonic acid 3,3-dimethyl-1-(toluene-4-sulfonyl)-aziridin-2-ylmethyl ester
• CAS NO: 369354-91-6
• Molecular Weight: 409.527
• Mol File: 369354-91-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: toluene-4-sulfonic acid 3,3-dimethyl-1-(toluene-4-sulfonyl)-aziridin-2-ylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: toluene-4-sulfonic acid 3,3-dimethyl-1-(toluene-4-sulfonyl)-aziridin-2-ylmethyl ester(369354-91-6)
• EPA Substance Registry System: toluene-4-sulfonic acid 3,3-dimethyl-1-(toluene-4-sulfonyl)-aziridin-2-ylmethyl ester(369354-91-6)

Safety Data

• Hazardous Substances Data: 369354-91-6(Hazardous Substances Data)

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 210972-38-6 (3,3-dimethyl-1-tosylaziridin-2-yl)methanol 

Downstream Products

• 90036-69-4 4-methyl-N-(1,1-dimethyl-2-propenyl)benzenesulfonamide 
• 1239889-01-0 C₁₂H₁₇NO₂S₂ 
• 1239889-02-1 N-(3,3-dimethyl-1,2-dithiolan-4-yl)-4-methylbenzenesulfonamide 

Relevant articles and documents

Tetrathiomolybdate mediated rearrangement of aziridinemethanol tosylates: A thia-aza-payne rearrangement

Aziridinemethanol sulfonate esters react with tetrathiomolybdate 1 to give thiirane derivatives as the major product and cyclic disulfides as minor product under mild reaction conditions via an unprecedented thia-aza-Payne-type rearrangement. Interestingly, when the reaction of 1 was carried out with 2-aziridino-cyclohexanol derivatives it resulted in the formation of thia-bicyclo[3.1.1]heptane or dithia-bicyclo[3.2.1]octane derivatives.